Molecular dynamics of cis-1-(2-hydroxy-5- methylphenyl)ethanone oxime and N-(2-hydroxy-4-methylphenyl)acetamide in solution studied by NMR spectroscopy
2010 John Wiley & Sons, Ltd.
| Publié dans: | Magnetic resonance in chemistry : MRC. - 1985. - 48(2010), 9 vom: 28. Sept., Seite 671-7 |
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| Auteur principal: | |
| Autres auteurs: | , , , |
| Format: | Article en ligne |
| Langue: | English |
| Publié: |
2010
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| Accès à la collection: | Magnetic resonance in chemistry : MRC |
| Sujets: | Journal Article 1-(2-hydroxy-5-methylphenyl)ethanone oxime Benzeneacetamides N-(2-hydroxy-4-methylphenyl)acetamide Oximes Phenols Solutions |
| Résumé: | 2010 John Wiley & Sons, Ltd. The formation of hydrogen bonds and molecular dynamics for the molecules cis-1-(2-hydroxy-5-methylphenyl)ethanone oxime (I) and N-(2-hydroxy-4-methylphenyl)acetamide (II) have been investigated in solution using NMR. The results confirm the formation of O-H...O, O-H...N and O...H-N type inter- and intramolecular hydrogen bonds. Spin-lattice relaxation times (T(1)), activation energy of molecular dynamics and energy of intramolecular hydrogen bonds have been determined |
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| Description: | Date Completed 20.01.2011 Date Revised 02.09.2010 published: Print Citation Status MEDLINE |
| ISSN: | 1097-458X |
| DOI: | 10.1002/mrc.2644 |