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231223s2010 xx |||||o 00| ||eng c |
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|a 10.1002/mrc.2637
|2 doi
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|a pubmed24n0664.xml
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|a eng
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|a Takacs, Z
|e verfasserin
|4 aut
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|a NMR investigation of guest-host complex between chloroform and cryptophane C
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|c 2010
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
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|a Date Completed 20.01.2011
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|a Date Revised 25.11.2016
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|a published: Print
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|a Citation Status MEDLINE
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|a 2010 John Wiley & Sons, Ltd.
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|a Guest-host complex between cryptophane C, possessing two non-equivalent caps, and chloroform is investigated by NMR spectroscopy. The kinetics of the chloroform exchange between the bound and free sites is determined by (1)H exchange spectroscopy. Moreover, the preferential orientation of chloroform molecule with respect to the cryptophane C frame is examined by the NOESY and ROESY experiments. The experimental findings are compared to the results of quantum chemical calculations
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|a Journal Article
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|a Research Support, Non-U.S. Gov't
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|a Bridged-Ring Compounds
|2 NLM
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|a Phenyl Ethers
|2 NLM
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|a Chloroform
|2 NLM
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|a 7V31YC746X
|2 NLM
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|a Soltésová, M
|e verfasserin
|4 aut
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|a Kotsyubynskyy, D
|e verfasserin
|4 aut
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|a Kowalewski, J
|e verfasserin
|4 aut
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|a Lang, J
|e verfasserin
|4 aut
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|a Brotin, T
|e verfasserin
|4 aut
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|a Dutasta, J P
|e verfasserin
|4 aut
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|i Enthalten in
|t Magnetic resonance in chemistry : MRC
|d 1985
|g 48(2010), 8 vom: 01. Aug., Seite 623-9
|w (DE-627)NLM098179667
|x 1097-458X
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|g volume:48
|g year:2010
|g number:8
|g day:01
|g month:08
|g pages:623-9
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|u http://dx.doi.org/10.1002/mrc.2637
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