Rapid, reversible preparation of size-controllable silver nanoplates by chemical redox

Citrate-stabilized silver nanoplates (AgNPs) were prepared using a seed-mediated growth method. The AgNP shape and size were controlled using potassium permanganate (KMnO(4)) as an oxidant and ascorbic acid (AA) as a reductant. Using KMnO(4), 42 nm nanoplates were changed to 22.9 nm nanodisks becaus...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 26(2010), 14 vom: 20. Juli, Seite 11621-3
1. Verfasser: Roh, Jinkyu (VerfasserIn)
Weitere Verfasser: Yi, Jongheop, Kim, Younghun
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2010
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article Research Support, Non-U.S. Gov't Silver 3M4G523W1G
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520 |a Citrate-stabilized silver nanoplates (AgNPs) were prepared using a seed-mediated growth method. The AgNP shape and size were controlled using potassium permanganate (KMnO(4)) as an oxidant and ascorbic acid (AA) as a reductant. Using KMnO(4), 42 nm nanoplates were changed to 22.9 nm nanodisks because of the release of silver ions. Using AA, the oxidized AgNPs were resynthesized to their initial plate form. These results are similar to those obtained using photoinduced shape control of silver nanoparticles; however, the chemical oxidation/reduction method can control the shape of AgNPs, both quantitatively and reversibly. In addition, because of redox-related visible spectral changes, solution color varies with AgNPs size. That feature may be useful in various applications 
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