Role of surfaces and interfaces in controlling the mechanical properties of metallic alloys

This article explores the subtle effects of surfaces and interfaces on the mechanical properties of bulk metallic alloys using three examples: environmental effects on fatigue life, hydrogen embrittlement effects on the ductility of intermetallics, and the role of coherent precipitates in the toughn...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 26(2010), 21 vom: 02. Nov., Seite 16254-60
1. Verfasser: Lee, Won-Jong (VerfasserIn)
Weitere Verfasser: Chia, Wen-Jui, Wang, Jinliu, Chen, Yanfeng, Vaynman, Semyon, Fine, Morris E, Chung, Yip-Wah
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2010
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article Research Support, Non-U.S. Gov't Research Support, U.S. Gov't, Non-P.H.S. Alloys Water 059QF0KO0R Nickel 7OV03QG267 Hydrogen 7YNJ3PO35Z mehr... Aluminum CPD4NFA903 Iron E1UOL152H7 Boron N9E3X5056Q Oxygen S88TT14065
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520 |a This article explores the subtle effects of surfaces and interfaces on the mechanical properties of bulk metallic alloys using three examples: environmental effects on fatigue life, hydrogen embrittlement effects on the ductility of intermetallics, and the role of coherent precipitates in the toughness of steels. It is demonstrated that the marked degradation of the fatigue life of metals is due to the strong chemisorption of adsorbates on exposed slip steps that are formed during fatigue deformation. These adsorbates reduce the reversibility of slip, thus accelerating fatigue damage in a chemically active gas environment. For certain intermetallic alloys such as Ni(3)Al and Ni(3)Fe, the ductility depends on the ambient gas composition and the atomic ordering in these alloys, both of which govern the complex surface chemical reactions taking place in the vicinity of crack tips. Finally, it is shown that local stresses at a coherent precipitate-matrix interface can activate dislocation motion at low temperatures, thus improving the fracture toughness of bulk alloys such as steels at cryogenic temperatures. These examples illustrate the complex interplay between surface chemistry and mechanics, often yielding unexpected results 
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650 4 |a Research Support, U.S. Gov't, Non-P.H.S. 
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650 7 |a Boron  |2 NLM 
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650 7 |a Oxygen  |2 NLM 
650 7 |a S88TT14065  |2 NLM 
700 1 |a Chia, Wen-Jui  |e verfasserin  |4 aut 
700 1 |a Wang, Jinliu  |e verfasserin  |4 aut 
700 1 |a Chen, Yanfeng  |e verfasserin  |4 aut 
700 1 |a Vaynman, Semyon  |e verfasserin  |4 aut 
700 1 |a Fine, Morris E  |e verfasserin  |4 aut 
700 1 |a Chung, Yip-Wah  |e verfasserin  |4 aut 
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