Seedless polyol synthesis and CO oxidation activity of monodisperse (111)- and (100)-oriented rhodium nanocrystals in sub-10 nm sizes

Monodisperse sub-10 nm (6.5 nm) sized Rh nanocrystals with (111) and (100) surface structures were synthesized by a seedless polyol reduction in ethylene glycol, with poly(vinylpyrrolidone) as a capping ligand. When using [Rh(Ac)(2)](2) as the metal precursor, (111)-oriented Rh nanopolyhedra contain...

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Détails bibliographiques
Publié dans:Langmuir : the ACS journal of surfaces and colloids. - 1985. - 26(2010), 21 vom: 02. Nov., Seite 16463-8
Auteur principal: Zhang, Yawen (Auteur)
Autres auteurs: Grass, Michael E, Huang, Wenyu, Somorjai, Gabor A
Format: Article en ligne
Langue:English
Publié: 2010
Accès à la collection:Langmuir : the ACS journal of surfaces and colloids
Sujets:Journal Article Research Support, Non-U.S. Gov't Organometallic Compounds Polymers polyol Carbon Monoxide 7U1EE4V452 Rhodium DMK383DSAC