Synthesis of zeolite phases from combustion by-products

Synthesis of zeolites from combustion by-products, including fly ash, bottom ash and rice husk ash, was studied. A molar ratio of SiO2/Al2O3 of 1.5 was used for the syntheses. Refluxing and hydrothermal methods were also used for synthesis for comparison. The reaction temperatures of refluxing and h...

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Veröffentlicht in:Waste management & research : the journal of the International Solid Wastes and Public Cleansing Association, ISWA. - 1991. - 28(2010), 12 vom: 15. Dez., Seite 1122-32
1. Verfasser: Pimraksa, Kedsarin (VerfasserIn)
Weitere Verfasser: Chindaprasirt, Prinya, Setthaya, Naruemon
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2010
Zugriff auf das übergeordnete Werk:Waste management & research : the journal of the International Solid Wastes and Public Cleansing Association, ISWA
Schlagworte:Journal Article Research Support, Non-U.S. Gov't Aluminum Compounds Coal Ash Industrial Waste Particulate Matter Zeolites 1318-02-1 Carbon 7440-44-0 mehr... Silicon Dioxide 7631-86-9
Beschreibung
Zusammenfassung:Synthesis of zeolites from combustion by-products, including fly ash, bottom ash and rice husk ash, was studied. A molar ratio of SiO2/Al2O3 of 1.5 was used for the syntheses. Refluxing and hydrothermal methods were also used for synthesis for comparison. The reaction temperatures of refluxing and hydrothermal methods were 100 degrees C and 130 degrees C, respectively. Sodalite, phillipsite-K, and zeolite P1 with analcime were obtained when fly ash, bottom ash and rice husk ash were used as starting materials, respectively. With rice husk ash as a starting material, zeolite P1 was produced. This result had advantages over previous studies as there was no prior activation required for the synthesis. The concentrations and types of alkaline used in the synthesis also determined the zeolite type. The different zeolites obtained from three systems were measured for specific surface area and pore size by using BET and Hg-porosimetry, respectively. Ammonium exchange capacities of the synthesised powders containing zeolites, sodalite, zeolite P1 and phillipsite-K were 38.5, 65.0 and 154.7 meq 100 g(-1), respectively
Beschreibung:Date Completed 18.03.2011
Date Revised 21.09.2015
published: Print-Electronic
Citation Status MEDLINE
ISSN:1096-3669
DOI:10.1177/0734242X09360366