Electrochemical-assisted encapsulation of catechol on a multiwalled carbon nanotube modified electrode
Electrochemical-assisted encapsulation of a neurotransmitter, catechol (CA), as nanoaggregates on a multiwalled carbon nanotube (>90% of carbon basis MWNT) modified gold electrode (Au/CACNT) has been demonstrated without any derivatization or electrode preactivation procedures. Characterization o...
| Veröffentlicht in: | Langmuir : the ACS journal of surfaces and colloids. - 1985. - 26(2010), 10 vom: 18. Mai, Seite 6874-7 |
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| Format: | Online-Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2010
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| Zugriff auf das übergeordnete Werk: | Langmuir : the ACS journal of surfaces and colloids |
| Schlagworte: | Journal Article Research Support, Non-U.S. Gov't Catechols Nanotubes, Carbon Gold 7440-57-5 catechol LF3AJ089DQ |
| Zusammenfassung: | Electrochemical-assisted encapsulation of a neurotransmitter, catechol (CA), as nanoaggregates on a multiwalled carbon nanotube (>90% of carbon basis MWNT) modified gold electrode (Au/CACNT) has been demonstrated without any derivatization or electrode preactivation procedures. Characterization of the CA@CNT by transmission electron microscopy (TEM), scanning electron microscopy (SEM), X-ray diffraction (XRD), Fourier transform infrared attenuated total reflection (FTIR/ATR) spectroscopy, and cyclic voltammetry (CV) collectively revealed stable encapsulation of the CA within strained and misalignment areas of the MWNT capsule. The Au/CA@CNT shows a couple of redox peaks centered at 0 (A1/C1) and 200 mV vs Ag/AgCl (A2/C2) due to the encapsulated (chemisorbed) and physisorbed CA moieties, respectively. The calculated chemisorbed catechol surface excess, Gamma(CA), value was 98.3 x 10(-10) mol x cm(-2). Control solution phase preparations of CA@CNTs yielded poor loading and instability problems, if it is chemically modified on the gold electrode. Electrochemical mediated oxidation of hydrazine on the Au/CA@CNT was demonstrated with an approximately 20 times increase in peak current and 200 mV reduction in the overpotential values in a pH 7 phosphate buffer solution |
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| Beschreibung: | Date Completed 17.08.2010 Date Revised 15.11.2012 published: Print Citation Status MEDLINE |
| ISSN: | 1520-5827 |
| DOI: | 10.1021/la100462r |