Intercalated water in synthetic fluorhectorite clay

(7)Li and (1)H nuclear magnetic resonance together with X-ray diffraction measurements in powdered samples and pseudocrystalline films of synthetic fluorhectorite as a function of relative ambient humidity permit to address several aspects of the structure and dynamics of intercalated water molecule...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1999. - 26(2010), 12 vom: 15. Juni, Seite 9703-9
1. Verfasser: Tenório, Rômulo P (VerfasserIn)
Weitere Verfasser: Engelsberg, M, Fossum, Jon Otto, da Silva, Geraldo J
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2010
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
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520 |a (7)Li and (1)H nuclear magnetic resonance together with X-ray diffraction measurements in powdered samples and pseudocrystalline films of synthetic fluorhectorite as a function of relative ambient humidity permit to address several aspects of the structure and dynamics of intercalated water molecules. The role of proton exchange as a possibly dominant mechanism of charge transport in the one-water layer regime of hydration is reexamined. The experimental results in Li-fluorhectorite support the result of molecular simulations which predict, for Li-montmorillonite, the existence of an intermediate regime, between one-water layer and two-water layer states 
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700 1 |a Fossum, Jon Otto  |e verfasserin  |4 aut 
700 1 |a da Silva, Geraldo J  |e verfasserin  |4 aut 
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