Bifunctional nanocatalyst of bimetallic nanoparticle/TiO2 with enhanced performance in electrochemical and photoelectrochemical applications

A novel metal/semiconductor hybrid nanostructure with enhanced catalytic functions has been prepared by a simple self-assembly approach. This new bifunctional nanocatalyst consists of evenly dispersed Au/Pt hybrid nanoparticles (Au/Pt NPs) assembled on NH(2) group functionalized anatase TiO(2) collo...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 26(2010), 13 vom: 06. Juli, Seite 11401-6
1. Verfasser: Wen, Dan (VerfasserIn)
Weitere Verfasser: Guo, Shaojun, Wang, Yizhe, Dong, Shaojun
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2010
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article Research Support, Non-U.S. Gov't titanium dioxide 15FIX9V2JP Titanium D1JT611TNE
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520 |a A novel metal/semiconductor hybrid nanostructure with enhanced catalytic functions has been prepared by a simple self-assembly approach. This new bifunctional nanocatalyst consists of evenly dispersed Au/Pt hybrid nanoparticles (Au/Pt NPs) assembled on NH(2) group functionalized anatase TiO(2) colloid spheres with nanoporous surface (f-TiO(2)). The resulting bimetallic nanoparticles/TiO(2) (noted as f-TiO(2)-Au/Pt NPs) hybrid nanostructure is characterized by various methods and expected as a promising catalyst in electrochemical and photoelectrochemical applications because of its satisfactory or even enhanced catalytic properties from both TiO(2) and Au/Pt NPs. Compared with the f-TiO(2), the electrochemical results indicate that the as-prepared f-TiO(2)-Au/Pt NPs exhibited more prominent electrocatalytic reduction toward hydrogen peroxide at low potential, which was then used as a sensitive sensor with a detection limit of 75 nM. Most importantly, the present hybrid material has the better photocatalytic property, as demonstrated by the photoelectrochemical catalysis of glucose 
650 4 |a Journal Article 
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700 1 |a Guo, Shaojun  |e verfasserin  |4 aut 
700 1 |a Wang, Yizhe  |e verfasserin  |4 aut 
700 1 |a Dong, Shaojun  |e verfasserin  |4 aut 
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