Initial spreading kinetics of high-viscosity droplets on anisotropic surfaces
Liquid droplets on chemically patterned surfaces consisting of alternating hydrophilic and hydrophobic stripes exhibit an elongated shape. To assess the dynamics during droplet formation, we present experimental results on the spreading of glycerol droplets on such surfaces using a high-speed camera...
| Veröffentlicht in: | Langmuir : the ACS journal of surfaces and colloids. - 1991. - 26(2010), 9 vom: 04. Mai, Seite 6328-34 |
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| Format: | Online-Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2010
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| Zugriff auf das übergeordnete Werk: | Langmuir : the ACS journal of surfaces and colloids |
| Schlagworte: | Journal Article |
| Zusammenfassung: | Liquid droplets on chemically patterned surfaces consisting of alternating hydrophilic and hydrophobic stripes exhibit an elongated shape. To assess the dynamics during droplet formation, we present experimental results on the spreading of glycerol droplets on such surfaces using a high-speed camera. Two spreading regimes are observed. Initially, in what is referred to as the inertial regime, the kinetics is dominated by the liquid and spreading is only weakly dependent on the specific surface properties. As such, liquid spreading is isotropic and the contact line maintains a circular shape. Our results reveal a remarkably long inertial regime, as compared to previous results and available models. Subsequently, in the viscous regime, interactions between the liquid and underlying pattern govern the dynamics. The droplet distorts from a spherical cap shape to adopt an elongated morphology that corresponds to the minimum energy configuration on stripe-patterned surfaces |
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| Beschreibung: | Date Completed 02.08.2010 Date Revised 27.04.2010 published: Print Citation Status PubMed-not-MEDLINE |
| ISSN: | 1520-5827 |
| DOI: | 10.1021/la903205e |