Synthesis of high quality MCM-48 with binary cationic-nonionic surfactants

Highly ordered MCM-48 was synthesized in the hydrothermal system of a mixture of cationic cetyltrimethylammonium bromide (CTAB) and nonionic poly(ethylene glycol) monooctylphenyl ether (Tx-100) using water glass as the silicon source. The effect of various factors, such as the amount of surfactant,...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 26(2010), 10 vom: 18. Mai, Seite 6982-8
1. Verfasser: Zhao, Wei (VerfasserIn)
Weitere Verfasser: Li, Quanzhi, Wang, Lina, Chu, Jinglong, Qu, Jinkui, Li, Shaohua, Qi, Tao
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2010
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article Research Support, Non-U.S. Gov't Cations Cetrimonium Compounds Surface-Active Agents polyethylene glycol monooctylphenyl ether Polyethylene Glycols 3WJQ0SDW1A Silicon Z4152N8IUI mehr... Cetrimonium Z7FF1XKL7A
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520 |a Highly ordered MCM-48 was synthesized in the hydrothermal system of a mixture of cationic cetyltrimethylammonium bromide (CTAB) and nonionic poly(ethylene glycol) monooctylphenyl ether (Tx-100) using water glass as the silicon source. The effect of various factors, such as the amount of surfactant, CTAB/Tx-100, Si source, crystallization temperature, and crystallization time, on the synthesis were discussed in detail. The local effective surfactant packing parameter theory and the charge balance theory were used to explain the reason that various factors can affect the product structure reasonably. Especially, the role of Tx-100 was expounded. The optimum synthesis conditions for MCM-48 were obtained 
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650 4 |a Research Support, Non-U.S. Gov't 
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700 1 |a Li, Quanzhi  |e verfasserin  |4 aut 
700 1 |a Wang, Lina  |e verfasserin  |4 aut 
700 1 |a Chu, Jinglong  |e verfasserin  |4 aut 
700 1 |a Qu, Jinkui  |e verfasserin  |4 aut 
700 1 |a Li, Shaohua  |e verfasserin  |4 aut 
700 1 |a Qi, Tao  |e verfasserin  |4 aut 
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