|
|
|
|
| LEADER |
01000naa a22002652 4500 |
| 001 |
NLM195600177 |
| 003 |
DE-627 |
| 005 |
20231223203040.0 |
| 007 |
tu |
| 008 |
231223s2009 xx ||||| 00| ||eng c |
| 028 |
5 |
2 |
|a pubmed24n0652.xml
|
| 035 |
|
|
|a (DE-627)NLM195600177
|
| 035 |
|
|
|a (NLM)20209023
|
| 040 |
|
|
|a DE-627
|b ger
|c DE-627
|e rakwb
|
| 041 |
|
|
|a eng
|
| 100 |
1 |
|
|a Stefik, Morgan
|e verfasserin
|4 aut
|
| 245 |
1 |
0 |
|a Ordered three- and five-ply nanocomposites from ABC block terpolymer microphase separation with niobia and aluminosilicate sols
|
| 264 |
|
1 |
|c 2009
|
| 336 |
|
|
|a Text
|b txt
|2 rdacontent
|
| 337 |
|
|
|a ohne Hilfsmittel zu benutzen
|b n
|2 rdamedia
|
| 338 |
|
|
|a Band
|b nc
|2 rdacarrier
|
| 500 |
|
|
|a Date Revised 20.11.2019
|
| 500 |
|
|
|a published: Print
|
| 500 |
|
|
|a Citation Status PubMed-not-MEDLINE
|
| 520 |
|
|
|a We report the first use of a non-frustrated block terpolymer for the synthesis of highly ordered oxide nanocomposites containing multiple plies. The morphological behavior of 15 ISO-oxide nanocomposites was investigated spanning a large range of compositions along the ƒ(I)=ƒ(S) isopleth using aluminosilicate and niobia sols. Morphologies were determined by TEM and SAXS measurements. Four morphologies were identified, including core-shell hexagonal, core-shell double gyroid, three-domain lamellae, and core-shell inverse-hexagonal, in order of increasing O+oxide vol fraction. All of the resulting nanocomposites had three- or five-ply morphologies containing domains that were continuous in one, two, or three dimensions. The five-ply core-shell double gyroid phase was only found to be stable when the O+oxide domain was a minority. Removal of the polymer enabled simple and direct synthesis of mesoporous oxide materials while retaining the ordered network structure. We believe that advances in the synthesis of multi-ply nanocomposites will lead to advanced materials and devices containing multiple plies of functional materials
|
| 650 |
|
4 |
|a Journal Article
|
| 700 |
1 |
|
|a Mahajan, Surbhi
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Sai, Hiroaki
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Epps, Thomas H
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Bates, Frank S
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Gruner, Sol M
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Disalvo, Francis J
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Wiesner, Ulrich
|e verfasserin
|4 aut
|
| 773 |
0 |
8 |
|i Enthalten in
|t Chemistry of materials : a publication of the American Chemical Society
|d 1998
|g 21(2009), 22 vom: 24. Nov., Seite 5466-5473
|w (DE-627)NLM098194763
|x 0897-4756
|7 nnns
|
| 773 |
1 |
8 |
|g volume:21
|g year:2009
|g number:22
|g day:24
|g month:11
|g pages:5466-5473
|
| 912 |
|
|
|a GBV_USEFLAG_A
|
| 912 |
|
|
|a SYSFLAG_A
|
| 912 |
|
|
|a GBV_NLM
|
| 912 |
|
|
|a GBV_ILN_11
|
| 912 |
|
|
|a GBV_ILN_350
|
| 951 |
|
|
|a AR
|
| 952 |
|
|
|d 21
|j 2009
|e 22
|b 24
|c 11
|h 5466-5473
|