Adsorption of nonionic and mixed nonionic/cationic surfactants onto hydrophilic and hydrophobic cellulose thin films
The adsorption of the nonionic surfactant hexaethylene monododecyl ether, C(12)E(6), and the mixed nonionic/cationic surfactants C(12)E(6) and hexadecyl trimethyl ammonium bromide, C(16)TAB, onto the hydrophilic and hydrophobic surfaces of thin cellulose films, formed by Langmuir-Blodgett, L-B, depo...
| Veröffentlicht in: | Langmuir : the ACS journal of surfaces and colloids. - 1992. - 26(2010), 11 vom: 01. Juni, Seite 8036-48 |
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| Format: | Online-Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2010
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| Zugriff auf das übergeordnete Werk: | Langmuir : the ACS journal of surfaces and colloids |
| Schlagworte: | Journal Article |
| Zusammenfassung: | The adsorption of the nonionic surfactant hexaethylene monododecyl ether, C(12)E(6), and the mixed nonionic/cationic surfactants C(12)E(6) and hexadecyl trimethyl ammonium bromide, C(16)TAB, onto the hydrophilic and hydrophobic surfaces of thin cellulose films, formed by Langmuir-Blodgett, L-B, deposition, have been studied by neutron reflectivity. For the surfactant mixtures, considerable nonideal mixing is observed at both hydrophobic and hydrophilic surfaces. The results demonstrate that the C(12)E(6), C(12)E(6)/C(16)TAB mixture and solvent have a greater penetration into the cellulose film upon adsorption, compared to that observed in previous studies of C(16)TAB adsorbed onto cellulose, due to the presence of the nonionic surfactant. From the range of measurements made, it is concluded that both the presence of the nonionic surfactant and the nature of the cellulose films are both contributing factors to this increased penetration and swelling of the cellulose film |
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| Beschreibung: | Date Completed 08.09.2010 Date Revised 25.05.2010 published: Print Citation Status PubMed-not-MEDLINE |
| ISSN: | 1520-5827 |
| DOI: | 10.1021/la1000057 |