Gold nanoparticle self-assembly in saturated phospholipid monolayers

Self-assembly of nanostructures on surfaces is a promising area in the emerging field of "bottom-up nanolithography". We describe a systematic analysis of hydrophobically capped gold nanoparticle (Au NP) assemblies created within monolayers of saturated phospholipids deposited at the air/w...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 26(2010), 11 vom: 01. Juni, Seite 7893-8
1. Verfasser: Mogilevsky, Alina (VerfasserIn)
Weitere Verfasser: Volinsky, Roman, Dayagi, Yohai, Markovich, Noa, Jelinek, Raz
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2010
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
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520 |a Self-assembly of nanostructures on surfaces is a promising area in the emerging field of "bottom-up nanolithography". We describe a systematic analysis of hydrophobically capped gold nanoparticle (Au NP) assemblies created within monolayers of saturated phospholipids deposited at the air/water interface. We show that the Au NPs are segregated within the mixed monolayers, forming distinct configurations. Microscopy analysis reveals that organized Au NP aggregates, including wires, rings, and "doughnut-shape" structures, are observed only within condensed-phase monolayers comprising phospholipids exhibiting longer acyl side-chains. In these monolayers, the Au NPs are localized at the edges of the condensed phospholipid domains. In addition to the pronounced effect of the phospholipid phases at the air/water interface, NP organization was found to depend upon the hydrophobic capping agents of the particles. The Au nanostructures assembled at the air/water interface can be transferred onto solid substrates, suggesting that the self-assembly monolayer approach could be exploited for practical nanoelectronic and sensing applications 
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700 1 |a Volinsky, Roman  |e verfasserin  |4 aut 
700 1 |a Dayagi, Yohai  |e verfasserin  |4 aut 
700 1 |a Markovich, Noa  |e verfasserin  |4 aut 
700 1 |a Jelinek, Raz  |e verfasserin  |4 aut 
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