Cracking of drying latex films : an ESEM experiment

In this study environmental scanning electron microscopy was used to observe the cracking of drying latex films below their glass-transition temperature. By controlling the relative humidity so that it decreases linearly with time, a critical level of humidity at which cracking occurs can be determi...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1985. - 26(2010), 11 vom: 01. Juni, Seite 7747-51
1. Verfasser: Dragnevski, Kalin I (VerfasserIn)
Weitere Verfasser: Routh, Alexander F, Murray, Martin W, Donald, Athene M
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2010
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
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520 |a In this study environmental scanning electron microscopy was used to observe the cracking of drying latex films below their glass-transition temperature. By controlling the relative humidity so that it decreases linearly with time, a critical level of humidity at which cracking occurs can be determined and this is measured as a function of film thickness. It was found that the cracking humidity decreases with increases in film thickness for thicknesses in the range of 30 to 100 mum and then remains almost unchanged. A scaling argument can be used to fit the data very well and indicates that cracking occurs as soon as the entire film is consolidated into close packing 
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700 1 |a Murray, Martin W  |e verfasserin  |4 aut 
700 1 |a Donald, Athene M  |e verfasserin  |4 aut 
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