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231223s2010 xx |||||o 00| ||eng c |
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|a 10.1021/la903414d
|2 doi
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|a eng
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| 100 |
1 |
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|a Wahab, M
|e verfasserin
|4 aut
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| 245 |
1 |
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|a Monte Carlo study of the self-assembly of achiral bolaform amphiphiles into helical nanofibers
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| 264 |
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|c 2010
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
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|2 rdamedia
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|a ƒa Online-Ressource
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|2 rdacarrier
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| 500 |
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|a Date Completed 28.05.2010
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|a Date Revised 23.02.2010
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|a published: Print
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|a Citation Status PubMed-not-MEDLINE
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|a It is shown by coarse-grained off-lattice Monte Carlo simulations that a geometrically induced frustration of the parallel arrangement of rigid achiral bolaform amphiphiles can cause chirality in self-assembled nanostructures. The amphiphilic molecules are represented as rigid linear chains of 8 equally sized hydrophobic spheres (tail) and a hydrophilic sphere (head) at each end. The hydrophilic and hydrophobic spheres differ in size. A very simple interaction scheme consisting of only hard-core repulsion between all spheres and square-well attraction between hydrophobic spheres is sufficient for self-assembly into helical fibers for molecules with head/tail diameter ratios ranging from 1.3 to 1.8
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| 650 |
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|a Journal Article
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1 |
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|a Schiller, P
|e verfasserin
|4 aut
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|a Schmidt, R
|e verfasserin
|4 aut
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| 700 |
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|a Mögel, H-J
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1999
|g 26(2010), 5 vom: 02. März, Seite 2979-82
|w (DE-627)NLM098181009
|x 1520-5827
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| 773 |
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|g volume:26
|g year:2010
|g number:5
|g day:02
|g month:03
|g pages:2979-82
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