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231223s2010 xx |||||o 00| ||eng c |
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|a 10.1021/la9038478
|2 doi
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|a eng
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|a Marmur, Abraham
|e verfasserin
|4 aut
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|a Correlating interfacial tensions with surface tensions
|b a gibbsian approach
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|c 2010
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
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|a ƒa Online-Ressource
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|a Date Completed 01.07.2010
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|a Date Revised 13.04.2010
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|a published: Print
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|a Citation Status PubMed-not-MEDLINE
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|a The Gibbs approach to the definition of interfacial and surface tensions is used for developing a general form for a correlation between interfacial tensions and their corresponding surface tensions. This general equation can serve as a starting point for either further fundamental development or an empirical search for a correlation that fits experimental data. In this Article, the latter approach is followed. The general equation is transformed by a few reasonable assumptions into a relatively simple framework for empirically correlating interfacial tensions with their corresponding surface tensions. The agreement of results of the present empirical correlation with a large body of experimental data for interfacial tensions in saturated liquid-liquid systems is better than that of previously suggested correlations. It is hoped that this correlation will be useful also for solid-liquid interfacial tensions, for which direct measurements are not yet available
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|a Journal Article
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|a Valal, Dorit
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|t Langmuir : the ACS journal of surfaces and colloids
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|g 26(2010), 8 vom: 20. Apr., Seite 5568-75
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