Controlled synthesis of dendritic gold nanostructures assisted by supramolecular complexes of surfactant with cyclodextrin

Controlled synthesis of well-defined planar Au nanodendrites with a symmetric single-crystalline structure consisting of trunks and side branches grown along the 211 directions was realized by reducing chloroauric acid in aqueous mixed solutions of dodecyltrimethylammonium bromide (DTAB) and beta-cy...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 26(2010), 10 vom: 18. Mai, Seite 7582-9
1. Verfasser: Huang, Teng (VerfasserIn)
Weitere Verfasser: Meng, Fei, Qi, Limin
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2010
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article Research Support, Non-U.S. Gov't Dendrimers Macromolecular Substances Quaternary Ammonium Compounds Surface-Active Agents beta-Cyclodextrins Gold 7440-57-5 dodecyltrimethylammonium mehr... GT3793XV5S betadex JV039JZZ3A
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520 |a Controlled synthesis of well-defined planar Au nanodendrites with a symmetric single-crystalline structure consisting of trunks and side branches grown along the 211 directions was realized by reducing chloroauric acid in aqueous mixed solutions of dodecyltrimethylammonium bromide (DTAB) and beta-cyclodextrin (beta-CD). It has been revealed that the formation of the supramolecular complexes of DTAB with beta-CD due to host-guest interaction is indispensable for the fabrication of these unique planar Au nanodendrites, and a proper CD-to-DTAB molar ratio is essential to their exclusive formation. A variety of Au nanostructures, such as branched particles consisting of rodlike branches and flowerlike particles consisting of platelike petals, could be readily obtained by simply changing the CD-to-DTAB molar ratio. Moreover, the obtained Au nanodendrites exhibited both a good electrocatalytic activity toward the oxidation of methanol and a good surface-enhanced Raman scattering (SERS) sensitivity for detecting p-aminothiophenol (PATP) molecules, indicating their potential applications including catalysis, biosensing, and nanodevices 
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700 1 |a Qi, Limin  |e verfasserin  |4 aut 
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