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231223s2010 xx |||||o 00| ||eng c |
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|a 10.1021/la9037815
|2 doi
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|a pubmed24n0646.xml
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|a (DE-627)NLM193853043
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|a (NLM)20020762
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|a DE-627
|b ger
|c DE-627
|e rakwb
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|a eng
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| 100 |
1 |
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|a Liang, Xiaohong
|e verfasserin
|4 aut
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| 245 |
1 |
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|a Fabrication of hierarchical CaCO3 mesoporous spheres
|b particle-mediated self-organization induced by biphase interfaces and SAMs
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|c 2010
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
|b c
|2 rdamedia
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|a ƒa Online-Ressource
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|2 rdacarrier
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|a Date Completed 01.07.2010
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|a Date Revised 01.12.2018
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|a published: Print
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|a Citation Status MEDLINE
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|a Highly ordered hierarchical calcium carbonate is an important phase involved in calcification by a wide variety of invertebrate organisms, and its formation is of technological interest in the development of functional materials. In this article, porous CaCO(3) hierarchical microspheres with a hedgehoglike appearance have been fabricated on the flexible substrate under mild conditions. There are two points that play important roles in the regular organization of the terminal products: one is the biphase interfaces, which are generated by organic solvent n-hexane and an aqueous saturated solution of Ca(OH)(2), and the other is hydroxyl-terminated monolayers assembled on the flexible PET (poly(ethylene terephthalate)) substrate. The SEM images show that novel CaCO(3) hierarchical microspheres consist of densely stacked "shuttles" by the oriented self-organization of CaCO(3) nanoparticles. The IR and XRD spectra indicate that the as-synthesized products are composed of a calcite phase obtained by an ACC (amorphous calcium carbonate)-to-calcite transformation. In view of the results, a nanoparticle-mediated self-organization process induced by biphase interfaces and SAMs template is proposed for the integration of functional materials and nanodevices
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|a Journal Article
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|a Research Support, Non-U.S. Gov't
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|a Polyethylene Terephthalates
|2 NLM
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|a Polyethylene Glycols
|2 NLM
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| 650 |
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|a 3WJQ0SDW1A
|2 NLM
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|a Calcium Carbonate
|2 NLM
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| 650 |
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|a H0G9379FGK
|2 NLM
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| 700 |
1 |
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|a Xiang, Junhui
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Zhang, Fushi
|e verfasserin
|4 aut
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| 700 |
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|a Xing, Li
|e verfasserin
|4 aut
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| 700 |
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|a Song, Bo
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Chen, Shiwei
|e verfasserin
|4 aut
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| 773 |
0 |
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 26(2010), 8 vom: 20. Apr., Seite 5882-8
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
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| 773 |
1 |
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|g volume:26
|g year:2010
|g number:8
|g day:20
|g month:04
|g pages:5882-8
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|u http://dx.doi.org/10.1021/la9037815
|3 Volltext
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