Solubilized derivatives of perylenetetracarboxylic dianhydride (PTCDA) adsorbed on highly oriented pyrolytic graphite

The effect on 2D molecular crystallization caused by the addition of propylthioether side groups to the 3,4,9,10-perylenetetracarboxylic dianhydride (PTCDA) molecule is investigated using scanning tunneling microscopy (STM). The molecule was deposited from 1-phenyloctane onto highly oriented pyrolyt...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1991. - 26(2010), 6 vom: 16. März, Seite 3972-4
1. Verfasser: Russell, James C (VerfasserIn)
Weitere Verfasser: Blunt, Matthew O, Goretzki, Gudrun, Phillips, Anna G, Champness, Neil R, Beton, Peter H
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2010
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
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520 |a The effect on 2D molecular crystallization caused by the addition of propylthioether side groups to the 3,4,9,10-perylenetetracarboxylic dianhydride (PTCDA) molecule is investigated using scanning tunneling microscopy (STM). The molecule was deposited from 1-phenyloctane onto highly oriented pyrolytic graphite (HOPG) and imaged at the liquid-solid interface. We observe a different structure to previously reported arrangements of PTCDA due to the presence of the propylthioether side groups which inhibits the formation of the herringbone phase. A model, supported by calculations based on density functional theory, is proposed in which molecules form rows stabilized by hydrogen bonding 
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700 1 |a Goretzki, Gudrun  |e verfasserin  |4 aut 
700 1 |a Phillips, Anna G  |e verfasserin  |4 aut 
700 1 |a Champness, Neil R  |e verfasserin  |4 aut 
700 1 |a Beton, Peter H  |e verfasserin  |4 aut 
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