Selective formation and structural properties of rhombic dodecahedral [70]fullerene microparticles formed by reaction with aliphatic diamines

We have accomplished the selective formation of rhombic dodecahedral microparticles on the submicrometer to micrometer scale by the reaction of [70]fullerene (C(70)) with primary aliphatic diamines. The morphology of the resultant microparticles was analyzed by scanning electron microscopy, powder X...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 26(2010), 6 vom: 16. März, Seite 4274-80
1. Verfasser: Matsuoka, Ken-ichi (VerfasserIn)
Weitere Verfasser: Akiyama, Tsuyoshi, Yamada, Sunao
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2010
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article Research Support, Non-U.S. Gov't Diamines Fullerenes fullerene C70 115383-22-7
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520 |a We have accomplished the selective formation of rhombic dodecahedral microparticles on the submicrometer to micrometer scale by the reaction of [70]fullerene (C(70)) with primary aliphatic diamines. The morphology of the resultant microparticles was analyzed by scanning electron microscopy, powder X-ray diffraction, and other spectroscopic methods, demonstrating that the resultant particles held a rhombic dodecahedral shape having a simple cubic lattice structure and that primary aliphatic amines were mostly trapped inside the particles through electronic interaction between C(70) and amines. Furthermore, we have discovered interesting structural characteristics in which the incorporated amines could be removed from the C(70) microparticles or exchanged with other primary aliphatic diamines 
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700 1 |a Yamada, Sunao  |e verfasserin  |4 aut 
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