Structural-dependent photoactivities of TiO(2) nanoribbon for visible-light-induced H(2) evolution : the roles of nanocavities and alternate structures

Bicrystalline dehydrated nanoribbon (DNR) with alternate structure of TiO(2)(B) and anatase has been prepared by a short-time annealing method. It is photoactive for photocatalytic H(2) evolution from water in the visible region sensitized by a novel heteropoly blue sensitizer. The effects of anneal...

Ausführliche Beschreibung

Bibliographische Detailangaben
Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 26(2010), 1 vom: 05. Jan., Seite 447-55
1. Verfasser: Fu, Ning (VerfasserIn)
Weitere Verfasser: Wu, Yuqi, Jin, Zhiliang, Lu, Gongxuan
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2010
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
LEADER 01000naa a22002652 4500
001 NLM192628259
003 DE-627
005 20231223193342.0
007 cr uuu---uuuuu
008 231223s2010 xx |||||o 00| ||eng c
024 7 |a 10.1021/la902042a  |2 doi 
028 5 2 |a pubmed24n0642.xml 
035 |a (DE-627)NLM192628259 
035 |a (NLM)19891447 
040 |a DE-627  |b ger  |c DE-627  |e rakwb 
041 |a eng 
100 1 |a Fu, Ning  |e verfasserin  |4 aut 
245 1 0 |a Structural-dependent photoactivities of TiO(2) nanoribbon for visible-light-induced H(2) evolution  |b the roles of nanocavities and alternate structures 
264 1 |c 2010 
336 |a Text  |b txt  |2 rdacontent 
337 |a ƒaComputermedien  |b c  |2 rdamedia 
338 |a ƒa Online-Ressource  |b cr  |2 rdacarrier 
500 |a Date Completed 02.03.2010 
500 |a Date Revised 29.12.2009 
500 |a published: Print 
500 |a Citation Status PubMed-not-MEDLINE 
520 |a Bicrystalline dehydrated nanoribbon (DNR) with alternate structure of TiO(2)(B) and anatase has been prepared by a short-time annealing method. It is photoactive for photocatalytic H(2) evolution from water in the visible region sensitized by a novel heteropoly blue sensitizer. The effects of annealing temperature and time on the DNR phase transformation process have been investigated. These results reveal that the nanocavity structure of TiO(2)(B) exhibits a narrow band gap and improves its absorbance coefficient in the visible region. The alternate structures of TiO(2)(B) and anatase improve interfacial electron separation and transfer. Compared with normal phase junction, the smoothing alternate joints in the band structure of DNR-600-30 provide an effective route for the movement of holes and electrons. This unique alternate bicrystalline structure has a significant advantage on its applications in photocatalysis and nanodevices 
650 4 |a Journal Article 
700 1 |a Wu, Yuqi  |e verfasserin  |4 aut 
700 1 |a Jin, Zhiliang  |e verfasserin  |4 aut 
700 1 |a Lu, Gongxuan  |e verfasserin  |4 aut 
773 0 8 |i Enthalten in  |t Langmuir : the ACS journal of surfaces and colloids  |d 1992  |g 26(2010), 1 vom: 05. Jan., Seite 447-55  |w (DE-627)NLM098181009  |x 1520-5827  |7 nnns 
773 1 8 |g volume:26  |g year:2010  |g number:1  |g day:05  |g month:01  |g pages:447-55 
856 4 0 |u http://dx.doi.org/10.1021/la902042a  |3 Volltext 
912 |a GBV_USEFLAG_A 
912 |a SYSFLAG_A 
912 |a GBV_NLM 
912 |a GBV_ILN_22 
912 |a GBV_ILN_350 
912 |a GBV_ILN_721 
951 |a AR 
952 |d 26  |j 2010  |e 1  |b 05  |c 01  |h 447-55