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231223s2009 xx |||||o 00| ||eng c |
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|a 10.1021/la902945x
|2 doi
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|a pubmed25n0642.xml
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|a (NLM)19874029
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|e rakwb
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|a eng
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|a Sen, Rupam
|e verfasserin
|4 aut
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|a Layered transition metal carboxylates
|b efficient reusable heterogeneous catalyst for epoxidation of olefins
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|c 2009
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
|b c
|2 rdamedia
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|a ƒa Online-Ressource
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|a Date Completed 01.02.2010
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|a Date Revised 25.11.2009
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|a published: Print
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|a Citation Status MEDLINE
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|a Layered metal carboxylates [M(malonato)(H(2)O)(2)](n) (M = Ni(II) and Mn(II)) that have a claylike structure have been synthesized hydrothermally and characterized. The interlayer separation in these layered carboxylates is comparable to that of the intercalation distance of the naturally occurring clay materials or layered double hydroxides (LDHs). In this study, we have demonstrated that, instead of intercalating the metal complex into layers of the clay or LDH, layered transition metal carboxylates, [M(malonato)(H(2)O)(2)](n), as such can be used as a recyclable heterogeneous catalyst in olefin epoxidation reaction. Metal carboxylates [M(malonato)(H(2)O)(2)](n) exhibit excellent catalytic performance in olefin epoxidation reaction
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|a Journal Article
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|a Research Support, Non-U.S. Gov't
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|a Alkenes
|2 NLM
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|a Carboxylic Acids
|2 NLM
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| 650 |
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|a Epoxy Compounds
|2 NLM
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|a Organometallic Compounds
|2 NLM
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| 700 |
1 |
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|a Bhunia, Susmita
|e verfasserin
|4 aut
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|a Mal, Dasarath
|e verfasserin
|4 aut
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| 700 |
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|a Koner, Subratanath
|e verfasserin
|4 aut
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|a Miyashita, Yoshitaro
|e verfasserin
|4 aut
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|a Okamoto, Ken-Ichi
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1991
|g 25(2009), 23 vom: 01. Dez., Seite 13667-72
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
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| 773 |
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|g volume:25
|g year:2009
|g number:23
|g day:01
|g month:12
|g pages:13667-72
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|u http://dx.doi.org/10.1021/la902945x
|3 Volltext
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