Sonication-induced molecular gels based on mono-cholesterol substituted quinacridone derivatives
A series of monocholesterol substituted quinacridone derivatives MCC(n) (n = 4, 6, 8) has been designed and synthesized. Compounds MCC(6) and MCC(8) can gelate a wide range of organic solvents upon ultrasound irradiation and afford intriguing well-defined nanostructures composed of three-dimensional...
Veröffentlicht in: | Langmuir : the ACS journal of surfaces and colloids. - 1992. - 26(2010), 3 vom: 02. Feb., Seite 2113-8 |
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Weitere Verfasser: | , , , , |
Format: | Online-Aufsatz |
Sprache: | English |
Veröffentlicht: |
2010
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Zugriff auf das übergeordnete Werk: | Langmuir : the ACS journal of surfaces and colloids |
Schlagworte: | Journal Article |
Zusammenfassung: | A series of monocholesterol substituted quinacridone derivatives MCC(n) (n = 4, 6, 8) has been designed and synthesized. Compounds MCC(6) and MCC(8) can gelate a wide range of organic solvents upon ultrasound irradiation and afford intriguing well-defined nanostructures composed of three-dimensional sponge-like superstructures or fibrous networks. Interestingly, the gel produced from MCC(6) is sensitive to thermo-, aniline, and formic acid stimulus, giving obviously different aggregation behaviors as well as physical properties. Time-dependent spectroscopic data and theoretical calculation results provided explanation for the possible molecular aggregation mode during the formation of the gels |
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Beschreibung: | Date Completed 24.03.2010 Date Revised 26.01.2010 published: Print Citation Status PubMed-not-MEDLINE |
ISSN: | 1520-5827 |
DOI: | 10.1021/la902663z |