Structural organization of iron oxide nanoparticles synthesized inside hybrid polymer gels derived from alginate studied with small-angle X-ray scattering

The structural organization of iron oxide nanoparticles (NPs) obtained through in situ coprecipitation of iron salts in semi-interpenetrating polymer networks (semi-IPNs) constituted of alginate (Alg) and poly(N-isopropylacrylamide) (PNiPAAm) has been investigated by means of small-angle X-ray scatt...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 25(2009), 22 vom: 17. Nov., Seite 13212-8
1. Verfasser: Hernández, Rebeca (VerfasserIn)
Weitere Verfasser: Sacristán, Javier, Nogales, Aurora, Ezquerra, Tiberio A, Mijangos, Carmen
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2009
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article Research Support, Non-U.S. Gov't Alginates Ferric Compounds Hexuronic Acids Polymers ferric oxide 1K09F3G675 Glucuronic Acid 8A5D83Q4RW
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520 |a The structural organization of iron oxide nanoparticles (NPs) obtained through in situ coprecipitation of iron salts in semi-interpenetrating polymer networks (semi-IPNs) constituted of alginate (Alg) and poly(N-isopropylacrylamide) (PNiPAAm) has been investigated by means of small-angle X-ray scattering and transmission electron microscopy. The oxidation reaction was repeated up to two times to increase the amount of iron oxide NPs formed. The results were compared to the synthesis of iron oxide nanoparticles in an alginate solution. It has been demonstrated that the polymeric gel acts as a spatial framework for iron oxide nanoparticles that controls their particle size distribution and that the application of repeating oxidation cycles does not increase the polydispersity of the iron oxide nanoparticles 
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650 4 |a Research Support, Non-U.S. Gov't 
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700 1 |a Sacristán, Javier  |e verfasserin  |4 aut 
700 1 |a Nogales, Aurora  |e verfasserin  |4 aut 
700 1 |a Ezquerra, Tiberio A  |e verfasserin  |4 aut 
700 1 |a Mijangos, Carmen  |e verfasserin  |4 aut 
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