Constant time gradient HSQC-iDOSY : practical aspects

Copyright 2009 John Wiley & Sons, Ltd.

Bibliographische Detailangaben
Veröffentlicht in:Magnetic resonance in chemistry : MRC. - 1985. - 47(2009), 12 vom: 02. Dez., Seite 1081-5
1. Verfasser: McLachlan, A S (VerfasserIn)
Weitere Verfasser: Richards, J J, Bilia, A R, Morris, G A
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2009
Zugriff auf das übergeordnete Werk:Magnetic resonance in chemistry : MRC
Schlagworte:Journal Article Research Support, Non-U.S. Gov't Carbon Isotopes Protons Rutin 5G06TVY3R7 Quercetin 9IKM0I5T1E
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520 |a An improved constant time gradient HSQC-iDOSY pulse sequence is presented, and the corresponding form of the Stejskal-Tanner equation is derived. The pulse sequence is particularly well suited to the problem of analysing mixtures of chemically cognate species, where the high spectral resolution afforded by 1H-13C correlation methods is needed for DOSY experiments to give good diffusion resolution. Its use is illustrated for a mixture of rutin and its aglycone quercetin 
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