Micro/nanobinary structure of silver films on copper alloys with stable water-repellent property under dynamic conditions

Facile galvanic replacement was adopted to grow cauliflower-like and dendrite coral-like silver films on commercial copper alloy substrates. Both types of silver films possess micro/nanobinary structures, the formation and evolution of which are achieved through the oriented attachment growth mechan...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 25(2009), 20 vom: 20. Okt., Seite 12299-307
1. Verfasser: Gu, Changdong (VerfasserIn)
Weitere Verfasser: Ren, Hang, Tu, Jiangping, Zhang, Tong-Yi
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2009
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
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520 |a Facile galvanic replacement was adopted to grow cauliflower-like and dendrite coral-like silver films on commercial copper alloy substrates. Both types of silver films possess micro/nanobinary structures, the formation and evolution of which are achieved through the oriented attachment growth mechanism. After modification by a monolayer of n-dodecanethiol, the cauliflower-like silver film becomes hydrophobic with a contact angle (CA) of 115 +/- 1 degrees and a CA hysteresis of 74 +/- 1 degrees and the dendrite coral-like silver film exhibits the extreme hydrophobicity characterized by a CA of 158 +/- 1 degrees and a CA hysteresis of less than 2 +/- 1 degrees . Furthermore, the bouncing property of millimeter-sized water droplets on the modified dendrite coral-like silver surface is much better than that on the modified cauliflower-like silver surface. The different wetting property between the two silver films is attributed to the surface roughness. Larger surface roughness provided by the dendrite coral-like silver film means more air pockets, among the micro/nanobinary structures, that bounce water droplets back more strongly. The dynamic bouncing behavior of water droplets, such as restitution coefficient and contact time, on the superhydrophobic modified cauliflower-like silver surface was also investigated at different impact velocities 
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700 1 |a Ren, Hang  |e verfasserin  |4 aut 
700 1 |a Tu, Jiangping  |e verfasserin  |4 aut 
700 1 |a Zhang, Tong-Yi  |e verfasserin  |4 aut 
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