Solvent extraction of organic acids from stillage for its re-use in ethanol production process

Stillage re-use in the fermentation stage in ethanol production is a technique used for the reduction of water and fermentation nutrients consumption. However, the inhibitory effect on yeast growth of the by-products and feed components that remains in stillage increases with re-use and reduces the...

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Veröffentlicht in:Waste management & research : the journal of the International Solid Wastes and Public Cleansing Association, ISWA. - 1991. - 28(2010), 6 vom: 01. Juni, Seite 533-8
1. Verfasser: Castro, G A (VerfasserIn)
Weitere Verfasser: Caicedo, L A, Alméciga-Díaz, C J, Sanchez, O F
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2010
Zugriff auf das übergeordnete Werk:Waste management & research : the journal of the International Solid Wastes and Public Cleansing Association, ISWA
Schlagworte:Journal Article Acids Organic Chemicals Plant Oils Solvents Ethanol 3K9958V90M Palm Oil 5QUO05548Z Acetic Acid Q40Q9N063P
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520 |a Stillage re-use in the fermentation stage in ethanol production is a technique used for the reduction of water and fermentation nutrients consumption. However, the inhibitory effect on yeast growth of the by-products and feed components that remains in stillage increases with re-use and reduces the number of possible recycles. Several methods such as ultrafiltration, electrodialysis and advanced oxidation processes have been used in stillage treatment prior its re-use in the fermentation stage. Nevertheless, few studies evaluating the effect of solvent extraction as a stillage treatment option have been performed. In this work, the inhibitory effect of serial stillage recycling over ethanol and biomass production was determined, using acetic acid as a monitoring compound during the fermentation and solvent extraction process. Raw palm oil methyl ester showed the highest acetic acid extraction from the aqueous phase, presenting a distribution coefficient of 3.10 for a 1:1 aqueous phase mixture:solvent ratio. Re-using stillage without treatment allowed up to three recycles with an ethanol production of 53.7 +/- 2.0 g L(-1), which was reduced 25% in the fifth recycle. Alternatively, treated stillage allowed up to five recycles with an ethanol final concentration of 54.7 +/- 1.3 g L(- 1). These results show that reduction of acetic acid concentration by an extraction process with raw palm oil methyl ester before re-using stillage improves the number of recycles without a major effect on ethanol production. The proposed process generates a palm oil methyl ester that contains organic acids, among other by-products, that could be used for product recovery and as an alternative fuel 
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650 7 |a Organic Chemicals  |2 NLM 
650 7 |a Plant Oils  |2 NLM 
650 7 |a Solvents  |2 NLM 
650 7 |a Ethanol  |2 NLM 
650 7 |a 3K9958V90M  |2 NLM 
650 7 |a Palm Oil  |2 NLM 
650 7 |a 5QUO05548Z  |2 NLM 
650 7 |a Acetic Acid  |2 NLM 
650 7 |a Q40Q9N063P  |2 NLM 
700 1 |a Caicedo, L A  |e verfasserin  |4 aut 
700 1 |a Alméciga-Díaz, C J  |e verfasserin  |4 aut 
700 1 |a Sanchez, O F  |e verfasserin  |4 aut 
773 0 8 |i Enthalten in  |t Waste management & research : the journal of the International Solid Wastes and Public Cleansing Association, ISWA  |d 1991  |g 28(2010), 6 vom: 01. Juni, Seite 533-8  |w (DE-627)NLM098164791  |x 1096-3669  |7 nnns 
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