Dispersion and film-forming properties of poly(acrylic acid)-stabilized carbon nanotubes

We present a detailed study of the influence of pH on the dispersion and film-forming properties of poly(acrylic acid)-stabilized carbon nanotubes. Poly(acrylic acid) (PAA) is a weak polyelectrolyte, with a pH-responsive behavior in aqueous solution. We obtain quantitative UV-visible measurements to...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 25(2009), 22 vom: 17. Nov., Seite 13206-11
1. Verfasser: Saint-Aubin, Karell (VerfasserIn)
Weitere Verfasser: Poulin, Philippe, Saadaoui, Hassan, Maugey, Maryse, Zakri, Cécile
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2009
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
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520 |a We present a detailed study of the influence of pH on the dispersion and film-forming properties of poly(acrylic acid)-stabilized carbon nanotubes. Poly(acrylic acid) (PAA) is a weak polyelectrolyte, with a pH-responsive behavior in aqueous solution. We obtain quantitative UV-visible measurements to show that the amount of polyelectrolyte in optimal pH conditions is weak, showing a good efficiency of the polymer as a carbon nanotube dispersing agent. The best dispersion conditions are achieved at pH 5, a value close to the pK(a) of PAA. Apart from this tenuous pH value, the PAA is not efficient at stabilizing nanotubes and atomic force microscopy allows us to explain the delicate balance between the PAA adsorption and the suspension stability. This study finally permits optimal conditions for making homogeneous and conductive composite films to be determined 
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700 1 |a Poulin, Philippe  |e verfasserin  |4 aut 
700 1 |a Saadaoui, Hassan  |e verfasserin  |4 aut 
700 1 |a Maugey, Maryse  |e verfasserin  |4 aut 
700 1 |a Zakri, Cécile  |e verfasserin  |4 aut 
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