Structure of partially fluorinated surfactant monolayers at the air-water interface

Partially fluorinated cationic surfactants of the form C(n)F(2n+1)C(m)H(2m)N(CH3)Br have been prepared, and their behavior at the air-water interface has been studied using surface tension measurements and neutron reflectometry. The degree of fluorination has been varied while keeping the overall ch...

Ausführliche Beschreibung

Bibliographische Detailangaben
Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 25(2009), 7 vom: 07. Apr., Seite 3957-65
1. Verfasser: Jackson, A J (VerfasserIn)
Weitere Verfasser: Li, P X, Dong, C C, Thomas, R K, Penfold, J
Format: Aufsatz
Sprache:English
Veröffentlicht: 2009
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
LEADER 01000naa a22002652 4500
001 NLM190992840
003 DE-627
005 20231223190353.0
007 tu
008 231223s2009 xx ||||| 00| ||eng c
028 5 2 |a pubmed24n0637.xml 
035 |a (DE-627)NLM190992840 
035 |a (NLM)19714885 
040 |a DE-627  |b ger  |c DE-627  |e rakwb 
041 |a eng 
100 1 |a Jackson, A J  |e verfasserin  |4 aut 
245 1 0 |a Structure of partially fluorinated surfactant monolayers at the air-water interface 
264 1 |c 2009 
336 |a Text  |b txt  |2 rdacontent 
337 |a ohne Hilfsmittel zu benutzen  |b n  |2 rdamedia 
338 |a Band  |b nc  |2 rdacarrier 
500 |a Date Completed 22.09.2009 
500 |a Date Revised 27.10.2019 
500 |a published: Print 
500 |a Citation Status PubMed-not-MEDLINE 
520 |a Partially fluorinated cationic surfactants of the form C(n)F(2n+1)C(m)H(2m)N(CH3)Br have been prepared, and their behavior at the air-water interface has been studied using surface tension measurements and neutron reflectometry. The degree of fluorination has been varied while keeping the overall chain lengths similar. The results are compared with those previously obtained for C16H33N(CH3)Br (C16TAB). The structural studies show a decrease in molecular orientation with increasing fluorination. The mean tilt away from the surface normal varies from 55 degrees for C16TAB to 25 degrees for C8F17C6H12N(CH3)Br. The interfacial layer roughness is observed to be lower than that expected for a pure fluorocarbon surfactant 
650 4 |a Journal Article 
700 1 |a Li, P X  |e verfasserin  |4 aut 
700 1 |a Dong, C C  |e verfasserin  |4 aut 
700 1 |a Thomas, R K  |e verfasserin  |4 aut 
700 1 |a Penfold, J  |e verfasserin  |4 aut 
773 0 8 |i Enthalten in  |t Langmuir : the ACS journal of surfaces and colloids  |d 1992  |g 25(2009), 7 vom: 07. Apr., Seite 3957-65  |w (DE-627)NLM098181009  |x 1520-5827  |7 nnns 
773 1 8 |g volume:25  |g year:2009  |g number:7  |g day:07  |g month:04  |g pages:3957-65 
912 |a GBV_USEFLAG_A 
912 |a SYSFLAG_A 
912 |a GBV_NLM 
912 |a GBV_ILN_22 
912 |a GBV_ILN_350 
912 |a GBV_ILN_721 
951 |a AR 
952 |d 25  |j 2009  |e 7  |b 07  |c 04  |h 3957-65