The chemical and oxidation characteristics of semi-dry flue gas desulfurization ash from a steel factory

Some samples of semi-dry flue gas desulfurization (FGD) ash were taken from sinter gas of a steel factory. Scanning electron microscope (SEM) and X-ray diffraction (XRD) analyses were employed to identify the samples in order to investigate their physical and chemical characteristics. The results sh...

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Publié dans:Waste management & research : the journal of the International Solid Wastes and Public Cleansing Association, ISWA. - 1991. - 28(2010), 10 vom: 01. Okt., Seite 865-71
Auteur principal: Liu, Ren-ping (Auteur)
Autres auteurs: Guo, Bin, Ren, Ailing, Bian, Jing-feng
Format: Article en ligne
Langue:English
Publié: 2010
Accès à la collection:Waste management & research : the journal of the International Solid Wastes and Public Cleansing Association, ISWA
Sujets:Journal Article Research Support, Non-U.S. Gov't Industrial Waste Steel 12597-69-2
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520 |a Some samples of semi-dry flue gas desulfurization (FGD) ash were taken from sinter gas of a steel factory. Scanning electron microscope (SEM) and X-ray diffraction (XRD) analyses were employed to identify the samples in order to investigate their physical and chemical characteristics. The results show that semi-dry FGD ash from a steel factory is stable under atmospheric conditions. It has irregular shape, a smooth surface and loose construction. The size of FGD ash particles is around 0.5-25 µm, the average size is about 5 µm and the median diameter is 4.18 µm. Semi-dry FGD ash from a steel factory consists of CaSO₃, CaSO₄, CaCO₃, some amorphous vitreous material and unburned carbon. An experimental method was found to study the oxidation characteristics of ash. A prediction model of the oxidation efficiency was obtained based on response surface methodology. The results show that not only the temperature, but also gas:solid ratio, play an important role in influencing the oxidation efficiency. The interactions of the gas:solid ratio with temperature play an essential role. An improved response surface model was obtained which can be helpful to describe the degree of oxidation efficiency of semi-dry FGD ash 
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