Plasmon-enhanced photocurrent generation from self-assembled monolayers of phthalocyanine by using gold nanoparticle films

The effect of localized electric fields on the photocurrent responses of phthalocyanine that was self-assembled on a gold nanoparticle film was investigated by comparing the conventional and the total internal reflection (TIR) experimental systems. In the case of photocurrent measurements, self-asse...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 25(2009), 6 vom: 09. Apr., Seite 3887-93
1. Verfasser: Sugawa, Kosuke (VerfasserIn)
Weitere Verfasser: Akiyama, Tsuyoshi, Kawazumi, Hirofumi, Yamada, Sunao
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2009
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article Colloids Indoles Ions Isoindoles Tin Compounds indium tin oxide 71243-84-0 Gold 7440-57-5 mehr... phthalocyanine V5PUF4VLGY
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245 1 0 |a Plasmon-enhanced photocurrent generation from self-assembled monolayers of phthalocyanine by using gold nanoparticle films 
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520 |a The effect of localized electric fields on the photocurrent responses of phthalocyanine that was self-assembled on a gold nanoparticle film was investigated by comparing the conventional and the total internal reflection (TIR) experimental systems. In the case of photocurrent measurements, self-assembled monolayers (SAMs) of a thiol derivative of palladium phthalocyanine (PdPc) were prepared on the surface of gold-nanoparticle film that was fixed on the surface of indium-tin-oxide (ITO) substrate via a polyion (PdPc/AuP/polyion/ITO) or on the ITO surface (PdPc/ITO). Photocurrent action spectra from the two samples were compared by using the conventional spectrometer, and were found that PdPc/AuP/polyion/ITO gave considerably larger photocurrent signals than PdPc/ITO under the identical concentration of PdPc. In the case of the TIR experiments for the PdPc/AuP/polyion/ITO and the PdPc/AuP/Glass systems, incident-angle profiles of photocurrent and emission signals were correlated with each other, and they were different from that of the PdPc/ITO system. Accordingly, it was demonstrated that the photocurrent signals were certainly enhanced by the localized electric fields of the gold-nanoparticle film 
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650 7 |a 71243-84-0  |2 NLM 
650 7 |a Gold  |2 NLM 
650 7 |a 7440-57-5  |2 NLM 
650 7 |a phthalocyanine  |2 NLM 
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700 1 |a Akiyama, Tsuyoshi  |e verfasserin  |4 aut 
700 1 |a Kawazumi, Hirofumi  |e verfasserin  |4 aut 
700 1 |a Yamada, Sunao  |e verfasserin  |4 aut 
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773 1 8 |g volume:25  |g year:2009  |g number:6  |g day:09  |g month:04  |g pages:3887-93 
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