Preparation, characterization, and catalytic activity of core/shell Fe3O4polyaniline@au nanocomposites

We report a new method to synthesize magnetically responsive Fe3O4polyaniline@Au nanocomposites. The superparamagnetic Fe3O4@polyaniline with well-defined core/shell nanostructure has been synthesized via an ultrasound-assisted in situ surface polymerization method. The negatively charged Au nanopar...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 25(2009), 19 vom: 06. Okt., Seite 11835-43
1. Verfasser: Xuan, Shouhu (VerfasserIn)
Weitere Verfasser: Wang, Yi-Xiang J, Yu, Jimmy C, Leung, Ken Cham-Fai
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2009
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article Research Support, Non-U.S. Gov't Aniline Compounds polyaniline Gold 7440-57-5 Ferrosoferric Oxide XM0M87F357
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520 |a We report a new method to synthesize magnetically responsive Fe3O4polyaniline@Au nanocomposites. The superparamagnetic Fe3O4@polyaniline with well-defined core/shell nanostructure has been synthesized via an ultrasound-assisted in situ surface polymerization method. The negatively charged Au nanoparticles with a diameter of about 4 nm have been effectively assembled onto the positively charged surface of the as-synthesized Fe3O4@polyaniline core/shell microspheres via electrostatic attraction. The morphology, phase composition, and crystallinity of the as-prepared nanocomposites have been characterized by transmission electron microscopy (TEM) and powder X-ray diffraction (XRD). The central Fe3O4 cores are superparamagnetic at room temperature with strong magnetic response to externally applied magnetic field, thus providing a convenient means for separating the nanocomposite from solution. As-prepared inorganic/organic nanocomposite can be used as a magnetically recoverable nanocatalyst for the reduction of a selected substrate 
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700 1 |a Wang, Yi-Xiang J  |e verfasserin  |4 aut 
700 1 |a Yu, Jimmy C  |e verfasserin  |4 aut 
700 1 |a Leung, Ken Cham-Fai  |e verfasserin  |4 aut 
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