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231223s2009 xx |||||o 00| ||eng c |
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|a 10.1021/la901323d
|2 doi
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|a pubmed24n0633.xml
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|a (DE-627)NLM190010541
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|a (NLM)19603789
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|a DE-627
|b ger
|c DE-627
|e rakwb
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|a eng
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| 100 |
1 |
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|a Bang, Gyeong Sook
|e verfasserin
|4 aut
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| 245 |
1 |
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|a Adsorption of azothiophene dye having an N-bridging bidentate tail group on gold
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|c 2009
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
|b c
|2 rdamedia
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|a ƒa Online-Ressource
|b cr
|2 rdacarrier
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|a Date Completed 04.12.2009
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|a Date Revised 21.11.2013
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|a published: Print
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|a Citation Status MEDLINE
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|a The novel azothiophene derivatives [AT-di(CnSAc) (n=6 and 12)], an azo linkage (N=N) that bridges one phenyl ring with an N-bridging dialkylthioacetate tail and one thiophene ring, are synthesized and characterized. The azothiophene derivatives substituted with electron-withdrawing groups are blue in color, exhibit a bathochromic shift of a longer wavelength, and are electrochemically active. The formation and characterization of AT-di(CnSAc) SAMs with a bidentate tail group of the N-bridging dialkylthioacetate have been studied by surface sensitive techniques such as grazing angle Fourier transform infrared (FT-IR), a quartz crystal microbalance (QCM), spectroscopic ellipsometry, X-ray photoelectron spectroscopy (XPS), and cyclic voltammetry (CV). It has been shown that the adsorption reaction of the thioacetate group is almost spontaneous and the N-bridging dialkylthioacetate SAMs with longer methylene length have a packing density higher than that with a shorter methylene length. However, the sulfur tethers of the N-bridging dialkylthioacetate show incomplete binding of sulfur atoms in AT-di(CnSAc) SAMs
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|a Journal Article
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|a Research Support, Non-U.S. Gov't
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|a Buffers
|2 NLM
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|a Coloring Agents
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|a Sulfhydryl Compounds
|2 NLM
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|a Thiophenes
|2 NLM
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|a Sulfur
|2 NLM
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|a 70FD1KFU70
|2 NLM
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|a Gold
|2 NLM
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|a 7440-57-5
|2 NLM
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1 |
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|a Lee, Junghyun
|e verfasserin
|4 aut
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|a Baek, Hee Yoel
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Lee, Hyoyoung
|e verfasserin
|4 aut
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|a Jun, Kun
|e verfasserin
|4 aut
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| 700 |
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|a Shin, Seung Rim
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 25(2009), 18 vom: 15. Sept., Seite 10788-93
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
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| 773 |
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|g volume:25
|g year:2009
|g number:18
|g day:15
|g month:09
|g pages:10788-93
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|u http://dx.doi.org/10.1021/la901323d
|3 Volltext
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