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231223s2009 xx |||||o 00| ||eng c |
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|a 10.1021/la804317s
|2 doi
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|a pubmed24n0629.xml
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|a (DE-627)NLM188756892
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|a (NLM)19466788
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|a DE-627
|b ger
|c DE-627
|e rakwb
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| 041 |
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|a eng
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| 100 |
1 |
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|a Price, Eric W
|e verfasserin
|4 aut
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| 245 |
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|a Block copolymer strands with internal microphase separation structure via self-assembly at the air-water interface
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|c 2009
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
|b c
|2 rdamedia
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|a ƒa Online-Ressource
|b cr
|2 rdacarrier
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|a Date Completed 25.08.2009
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|a Date Revised 26.05.2009
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|a published: Print
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|a Citation Status PubMed-not-MEDLINE
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|a Block copolymer microphase separation in the bulk is coupled to amphiphilic block copolymer self-assembly at the air-water interface to yield hierarchical Langmuir-Blodgett (LB) structures combining organization at the meso- and nanoscales. A blend of polystyrene-b-poly(ethylene oxide) (PS-b-PEO) (Mn=141K, 11.4 wt % PEO) and polystyrene-b-poly(butadiene) (PS-b-PB) (Mn=31.9K, 28.5 wt % PB) containing a PS-b-PB weight fraction of f=0.75 was deposited at the air-water interface, resulting in the spontaneous generation of aggregates with multiscale organization, including nanoscale cylinders in mesoscale strands, via evaporation of the spreading solvent. The resulting features were characterized in LB films via AFM and TEM and at the air-water interface via Langmuir compression isotherms. Blends containing lower PS-b-PB contents formed mesoscale aggregate morphologies of continents and strands (f=0.50) or mesoscale continents with holes (f=0.25), but without the internal nanoscale organization found in the f=0.75 blend. The interfacial self-assembly of pure PS-b-PB at the air-water interface (f=1) yielded taller and more irregularly shaped aggregates than blends containing PS-b-PEO, indicating the integral role of the amphiphilic copolymer in regulating the mesoscale organization of the hierarchically structured features
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|a Journal Article
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1 |
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|a Guo, Yunyong
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Wang, C-W
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Moffitt, Matthew G
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 25(2009), 11 vom: 02. Juni, Seite 6398-406
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
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| 773 |
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|g volume:25
|g year:2009
|g number:11
|g day:02
|g month:06
|g pages:6398-406
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| 856 |
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|u http://dx.doi.org/10.1021/la804317s
|3 Volltext
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