Quasi-solid-state optical logic devices based on redox polymer nanosheet assembly

We report fabrication of a quasi-solid-state optical logic gate based on a polymer nanosheet photodiode. Two amphiphilic copolymers, p(DDA/Ru) and p(DDA/Fc), which respectively have a ruthenium dipyridyl complex and a ferrocene derivative as a redox molecule, are synthesized to produce redox polymer...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 25(2009), 18 vom: 15. Sept., Seite 11061-6
1. Verfasser: Matsui, Jun (VerfasserIn)
Weitere Verfasser: Abe, Kenichi, Mitsuishi, Masaya, Aoki, Atsushi, Miyashita, Tokuji
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2009
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
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520 |a We report fabrication of a quasi-solid-state optical logic gate based on a polymer nanosheet photodiode. Two amphiphilic copolymers, p(DDA/Ru) and p(DDA/Fc), which respectively have a ruthenium dipyridyl complex and a ferrocene derivative as a redox molecule, are synthesized to produce redox polymer nanosheets. To construct polymer nanosheet photodiodes, two redox polymer nanosheets were assembled onto an indium-tinoxide (ITO) electrode in a tailor-made manner. The ITO electrode was connected with a counter electrode using an agarose gel electrolyte. The simple two-electrode system performs as a quasi-solid-state polymer nanosheet photodiode (QS-PNP). The photocurrent flow direction of QS-PNP can be controlled to be anodic or be cathodic by changing the deposition order of the redox polymer nanosheets. The anodic and cathodic QS-PNPs were applied to construct optical OR and XOR logic gates. The OR logic gate was fabricated by connecting the anodic and cathodic QS-PNP in a series; XOR logic was fabricated by connecting two anodic QS-PNPs in series. In optical logic gates, excitations of p(DDA/Ru) were used as input signals, and photocurrent was used as an output signal. These optical logic gates operate in a quasi-solid-state in a simple two-electrode configuration, which facilitates integration of the logic elements 
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700 1 |a Abe, Kenichi  |e verfasserin  |4 aut 
700 1 |a Mitsuishi, Masaya  |e verfasserin  |4 aut 
700 1 |a Aoki, Atsushi  |e verfasserin  |4 aut 
700 1 |a Miyashita, Tokuji  |e verfasserin  |4 aut 
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