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231223s2009 xx |||||o 00| ||eng c |
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7 |
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|a 10.1021/la8034243
|2 doi
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|a pubmed25n0628.xml
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|a DE-627
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|e rakwb
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| 041 |
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|a eng
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| 100 |
1 |
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|a Xu, Yun-Xiang
|e verfasserin
|4 aut
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| 245 |
1 |
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|a Self-assembly of vesicles from amphiphilic aromatic amide-based oligomers
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| 264 |
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|c 2009
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| 336 |
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
|b c
|2 rdamedia
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|a ƒa Online-Ressource
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|2 rdacarrier
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|a Date Completed 01.07.2009
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|a Date Revised 21.11.2013
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|a published: Print
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|a Citation Status MEDLINE
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|a A novel class of linear arylamide oligomers has been designed and synthesized from naphthalene-2,7-diamine and benzene-1,3,5-tricarboxylic acid segments. The molecules carry two (tert-butoxycarbonylamino) groups at the ends and one to three hydrophilic N,N-bis(2-(2-(2-methoxyethoxy)ethoxy)ethyl)amino groups at one side of the backbone. The oligomers self-assembled into vesicular structures in methanol as a result of ordered stacking of the oligomeric amide backbones, which were evidenced by SEM, AFM, TEM, and fluorescent micrography experiments. It was also found that the tert-butoxycarbonylamino groups at the ends played an important role in promoting the ordered stacking of the backbones. Structural factors that affected the self-assembly of the oligomers were investigated. A two-layer model that was supported by TEM has been proposed for the formation of the vesicular structures, which was driven by both the hydrogen bonding and aromatic stacking
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|a Journal Article
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|a Research Support, Non-U.S. Gov't
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|a Amides
|2 NLM
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|a Polymers
|2 NLM
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|a Solvents
|2 NLM
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|a DNA
|2 NLM
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|a 9007-49-2
|2 NLM
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| 650 |
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|a Methanol
|2 NLM
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| 650 |
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|a Y4S76JWI15
|2 NLM
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| 700 |
1 |
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|a Wang, Gui-Tao
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Zhao, Xin
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Jiang, Xi-Kui
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Li, Zhan-Ting
|e verfasserin
|4 aut
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| 773 |
0 |
8 |
|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1991
|g 25(2009), 5 vom: 03. März, Seite 2684-8
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
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| 773 |
1 |
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|g volume:25
|g year:2009
|g number:5
|g day:03
|g month:03
|g pages:2684-8
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|u http://dx.doi.org/10.1021/la8034243
|3 Volltext
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