An investigation into advanced oxidation of three chlorophenoxy pesticides in surface water

The performance of Fenton's reagent in removing 2,4-D, MCPA and mecoprop from surface water has been evaluated here. Initial trials were undertaken at a pesticide concentration of 4.5 x 10(-5) mol l(-1) in deionised water at pH 3 and two different stoichiometric ratios of pesticide: Fe(II): H(2...

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Veröffentlicht in:Water science and technology : a journal of the International Association on Water Pollution Research. - 1986. - 59(2009), 8 vom: 26., Seite 1665-71
1. Verfasser: MacAdam, Jitka (VerfasserIn)
Weitere Verfasser: Parsons, Simon A
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2009
Zugriff auf das übergeordnete Werk:Water science and technology : a journal of the International Association on Water Pollution Research
Schlagworte:Journal Article Research Support, Non-U.S. Gov't Chlorophenols Fenton's reagent Pesticides Water Pollutants, Chemical Hydrogen Peroxide BBX060AN9V Iron E1UOL152H7
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245 1 3 |a An investigation into advanced oxidation of three chlorophenoxy pesticides in surface water 
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520 |a The performance of Fenton's reagent in removing 2,4-D, MCPA and mecoprop from surface water has been evaluated here. Initial trials were undertaken at a pesticide concentration of 4.5 x 10(-5) mol l(-1) in deionised water at pH 3 and two different stoichiometric ratios of pesticide: Fe(II): H(2)O(2) (1:1:10, 1:10:10) were evaluated. At the 1:1:10 ratio, approximately 10 minutes were required to achieve a 50% removal of the pesticide. At the higher ratio the removal achieved after 1 minute, was >90%. Subsequent experiments studied the performance of Fenton (4.5 x 10(-4) mol l(-1) Fe(II): 4.5 x 10(-4) mol l(-1) H(2)O(2)) in surface water spiked with pesticides and the impact of pH on the rate and degree of pesticide degradation was investigated. The removal was significantly improved at pH 3 in comparison to pH 6.5. The effect of Fenton on DOC removal from surface water was followed. Experiments investigated the performance of Fenton at pesticide concentrations of 7.5 x 10(-9) mol l(-1) in surface water. Fenton was shown to be an effective treatment for removing low levels of pesticides from surface waters at pH 3 & 4 
650 4 |a Journal Article 
650 4 |a Research Support, Non-U.S. Gov't 
650 7 |a Chlorophenols  |2 NLM 
650 7 |a Fenton's reagent  |2 NLM 
650 7 |a Pesticides  |2 NLM 
650 7 |a Water Pollutants, Chemical  |2 NLM 
650 7 |a Hydrogen Peroxide  |2 NLM 
650 7 |a BBX060AN9V  |2 NLM 
650 7 |a Iron  |2 NLM 
650 7 |a E1UOL152H7  |2 NLM 
700 1 |a Parsons, Simon A  |e verfasserin  |4 aut 
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