Preparation of P(NIPAM-co-AA) microcontainers surface-anchored with magnetic nanoparticles
P(NIPAM-co-AA) microcontainers surface-anchored with magnetic nanoparticles were prepared using PSt/P(NIPAM-co-AA) core/shell microspheres and amino-modified Fe(3)O(4)SiO(2) particles as building blocks. At first, the PSt/P(NIPAM-co-AA) core/shell microspheres were prepared by seeded emulsion polyme...
| Veröffentlicht in: | Langmuir : the ACS journal of surfaces and colloids. - 1992. - 25(2009), 14 vom: 21. Juli, Seite 8255-62 |
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| Format: | Online-Aufsatz |
| Sprache: | English |
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2009
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| Zugriff auf das übergeordnete Werk: | Langmuir : the ACS journal of surfaces and colloids |
| Schlagworte: | Journal Article Research Support, Non-U.S. Gov't Acrylamides N-isopropylacrylamide-acrylic acid copolymer Polymers |
| Zusammenfassung: | P(NIPAM-co-AA) microcontainers surface-anchored with magnetic nanoparticles were prepared using PSt/P(NIPAM-co-AA) core/shell microspheres and amino-modified Fe(3)O(4)SiO(2) particles as building blocks. At first, the PSt/P(NIPAM-co-AA) core/shell microspheres were prepared by seeded emulsion polymerization, and the amino-modified Fe(3)O(4)@SiO(2) particles were prepared by a modified Stober method followed by functionalized by 3-aminopropyltriethoxysilane. Then, the smaller amino-modified Fe(3)O(4)@SiO(2) particles were assembled onto the surface of PSt/P(NIPAM-co-AA) core/shell microspheres by electrostatic interaction. Subsequently, the two particles were permanently combined through amidation reaction between carboxylic groups and amino groups under the catalysis of 1-ethyl-3-(3-dimethylaminopropyl)carbodiimide and N-hydroxysuccinimide. By dissolving the PSt core with tetrahydrofuran, novel triple-functional microcontainers with superparamagnetism and pH and temperature sensitivity were obtained |
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| Beschreibung: | Date Completed 17.09.2009 Date Revised 14.07.2009 published: Print Citation Status MEDLINE |
| ISSN: | 1520-5827 |
| DOI: | 10.1021/la9004467 |