Encapsulation and Functionalization of Nanoparticles in Crosslinked Resorcinarene Shells
Two resorcinarene-derived tetrathiols with terminal alkene sidechains (tetraarylthiol cavitand 3 and tetrabenzylthiol cavitand 4) were determined to be efficient at extracting colloidal gold nanoparticles from aqueous solutions and stabilizing their dispersion in organic solvents. Treatment of these...
| Veröffentlicht in: | Journal of materials chemistry. - 1998. - 17(2007), 1 vom: 01. Jan., Seite 105-112 |
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| Weitere Verfasser: | , |
| Format: | Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2007
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| Zugriff auf das übergeordnete Werk: | Journal of materials chemistry |
| Schlagworte: | Journal Article |
| Zusammenfassung: | Two resorcinarene-derived tetrathiols with terminal alkene sidechains (tetraarylthiol cavitand 3 and tetrabenzylthiol cavitand 4) were determined to be efficient at extracting colloidal gold nanoparticles from aqueous solutions and stabilizing their dispersion in organic solvents. Treatment of these nanoparticle dispersions with the Grubbs olefin metathesis catalyst resulted in crosslinked resorcinarene shells that were highly resistant to alkanethiol-induced desorption at high temperatures. Nanoparticles in crosslinked shells of tetrabenzylthiol cavitand 4 were particularly robust, and could be precipitated and redispersed many times with minimal attrition. These shells could also withstand oxidative conditions and were amenable to synthetic modifications involving epoxidation and dihydroxylation |
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| Beschreibung: | Date Revised 20.10.2021 published: Print Citation Status PubMed-not-MEDLINE |
| ISSN: | 0959-9428 |