Adsorbable organic halogens generation and reduction during degradation of phenol by UV radiation/sodium hypochlorite

The degradation of phenol by UV radiation/sodium hypochlorite (UV/NaClO) was investigated. The degradation processes were analyzed by a UV-visible spectrometer, total organic carbon analyzer, and gas chromatography-mass spectroscopy. The experimental results indicate that phenol can be photodegraded...

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Publié dans:Water environment research : a research publication of the Water Environment Federation. - 1998. - 81(2009), 2 vom: 06. Feb., Seite 178-83
Auteur principal: Zeng, Qing-Fu (Auteur)
Autres auteurs: Fu, Jie, Shi, Yin-Tao, Xia, Dong-Sheng, Zhu, Hai-Liang
Format: Article
Langue:English
Publié: 2009
Accès à la collection:Water environment research : a research publication of the Water Environment Federation
Sujets:Journal Article Halogens Industrial Waste Water Pollutants, Chemical Phenol 339NCG44TV Sodium Hypochlorite DY38VHM5OD
Description
Résumé:The degradation of phenol by UV radiation/sodium hypochlorite (UV/NaClO) was investigated. The degradation processes were analyzed by a UV-visible spectrometer, total organic carbon analyzer, and gas chromatography-mass spectroscopy. The experimental results indicate that phenol can be photodegraded by UV/NaClO effectively. However, adsorbable organic halogens (AOX) were produced during the degradation process. Analysis of the mechanism of degradation indicates that the decrease in pH value would increase the formation of AOX. Also, dissolved oxygen greatly increased the rate of phenol degradation and reduced the formation of AOX. Therefore, appropriate conditions could increase degradation and inhibit chlorination. Adjusting the pH value and increasing the amount of oxygen were effective methods
Description:Date Completed 23.04.2009
Date Revised 23.09.2019
published: Print
Citation Status MEDLINE
ISSN:1061-4303