Two-component organogelators based on two L-amino acids : effect of combination of L-lysine with various L-amino acids on organogelation behavior
A two-component organogelation system, consisting of Nepsilon-dodecyl-L-lysine esters (amine components) and N-dodecyl-L-amino acids (valine, phenylalanine, alanine, glycine, L-lysine) as acid components, was proposed, and its organogelation properties were investigated. The mixture of amine and aci...
| Publié dans: | Langmuir : the ACS journal of surfaces and colloids. - 1985. - 25(2009), 15 vom: 04. Aug., Seite 8579-85 |
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| Auteur principal: | |
| Autres auteurs: | , |
| Format: | Article en ligne |
| Langue: | English |
| Publié: |
2009
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| Accès à la collection: | Langmuir : the ACS journal of surfaces and colloids |
| Sujets: | Journal Article Research Support, Non-U.S. Gov't Amines Amino Acids Gels Organic Chemicals Solvents Phenylalanine 47E5O17Y3R Lysine |
| Résumé: | A two-component organogelation system, consisting of Nepsilon-dodecyl-L-lysine esters (amine components) and N-dodecyl-L-amino acids (valine, phenylalanine, alanine, glycine, L-lysine) as acid components, was proposed, and its organogelation properties were investigated. The mixture of amine and acid components produced an organic salt compound through acid-base interactions, and it created a three-dimensional network by entangling self-assembled nanofibers through hydrogen bonding and van der Waals interactions, thus leading to the formation of organogels. The combination of Lys/Phe yielded rigid dodecane gel, and the gelators of Lys/ Lys yielded a thermally stable dodecane gel. The organogelation properties significantly depended on the combination of amine and acid components, and they could be controlled by the selection of suitable components |
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| Description: | Date Completed 19.01.2010 Date Revised 21.11.2013 published: Print Citation Status MEDLINE |
| ISSN: | 1520-5827 |
| DOI: | 10.1021/la8040924 |