Organogels based on 1H-imidazolecarboxamide amphiphiles
We prepared 1H-imidazolecarboxamide amphiphiles as potential organogelators. Compounds A1-A3, in which an imidazole head was connected to a hydrophobic trialkyloxyphenyl group, showed an ability to gelate nonpolar solvents, including alkanes. The dry gels obtained from compounds A1-A3 had columnar h...
| Veröffentlicht in: | Langmuir : the ACS journal of surfaces and colloids. - 1992. - 25(2009), 15 vom: 04. Aug., Seite 8439-41 |
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| Format: | Online-Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2009
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| Zugriff auf das übergeordnete Werk: | Langmuir : the ACS journal of surfaces and colloids |
| Schlagworte: | Journal Article |
| Zusammenfassung: | We prepared 1H-imidazolecarboxamide amphiphiles as potential organogelators. Compounds A1-A3, in which an imidazole head was connected to a hydrophobic trialkyloxyphenyl group, showed an ability to gelate nonpolar solvents, including alkanes. The dry gels obtained from compounds A1-A3 had columnar hexagonal structures. Polycatenar 1H-imidazolecarboxamide amphiphile B2, consisting of a 1H-imidazole head connected through a benzene ring to a tridecyloxyphenyl tail, formed an organogel in DMSO. In a concentrated THF solution (30 wt %), compound B2 exhibited a lyotropic liquid-crystalline phase with a columnar hexagonal structure. X-ray diffraction (XRD) results suggested a molecular arrangement consisting of a disk, via hydrogen bonding between successive imidazole moieties, and an assembly of columnar structures |
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| Beschreibung: | Date Completed 19.01.2010 Date Revised 16.12.2009 published: Print Citation Status PubMed-not-MEDLINE |
| ISSN: | 1520-5827 |
| DOI: | 10.1021/la804319e |