Performance of tetramethoxyphenyl porphyrin cobalt(II) (CoTMPP) based stainless steel cathode in the electricigenic permeable reactive barrier for groundwater organic contamination remediation

An electricigenic permeable reactive barrier (EPRB) technology was brought forward for remediation of organic-contaminated groundwater, with a benefit that it overcame the limitations of electron acceptor addition in other groundwater remediation methods. To investigate performances of constructions...

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Veröffentlicht in:Water science and technology : a journal of the International Association on Water Pollution Research. - 1986. - 59(2009), 5 vom: 24., Seite 979-85
1. Verfasser: Zhu, Shi-Kun (VerfasserIn)
Weitere Verfasser: Fan, Bin, Wu, Jie-Wei, Feng, Yuan-Yuan, Zhang, Yun
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2009
Zugriff auf das übergeordnete Werk:Water science and technology : a journal of the International Association on Water Pollution Research
Schlagworte:Journal Article Research Support, Non-U.S. Gov't Metalloporphyrins Water Pollutants, Chemical Stainless Steel 12597-68-1 Cobalt 3G0H8C9362
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520 |a An electricigenic permeable reactive barrier (EPRB) technology was brought forward for remediation of organic-contaminated groundwater, with a benefit that it overcame the limitations of electron acceptor addition in other groundwater remediation methods. To investigate performances of constructions and materials used in EPRB system, several kinds of reactors were designed and prepared in laboratory. Stainless steel wires, a kind of nontoxic, inexpensive and conductive material, were used as basic material of electrode. In order to improve cathodic oxygen reduction capability, a cathode based on tetramethoxyphenyl porphyrin cobalt (II) (CoTMPP) was prepared and studied in this paper. Results showed that a high catalytic activity for oxygen reduction was exhibited by the CoTMPP based cathode, with an electricity generation 3 times as high as that of the naked stainless steel cathode. Some evidence indicated that by loading on the surface of stainless steel wires and heat-treated under anaerobic conditions, epoxy resin, with its curing agents, might have got a catalytic capability for oxygen reduction 
650 4 |a Journal Article 
650 4 |a Research Support, Non-U.S. Gov't 
650 7 |a Metalloporphyrins  |2 NLM 
650 7 |a Water Pollutants, Chemical  |2 NLM 
650 7 |a Stainless Steel  |2 NLM 
650 7 |a 12597-68-1  |2 NLM 
650 7 |a Cobalt  |2 NLM 
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700 1 |a Fan, Bin  |e verfasserin  |4 aut 
700 1 |a Wu, Jie-Wei  |e verfasserin  |4 aut 
700 1 |a Feng, Yuan-Yuan  |e verfasserin  |4 aut 
700 1 |a Zhang, Yun  |e verfasserin  |4 aut 
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