Toward organization of cyano-bridged coordination polymer nanoparticles within an ionic liquid crystal

Size controlled cyano-bridged coordination polymer nanoparticles Mn1.5[Cr(CN)6] have been synthesized and organized at the nanolevel by using the room temperature ionic liquid crystal (ILC) C12-MIMBF4. The as-obtained material was studied by transmission electron microscopy (TEM), differential scann...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 25(2009), 2 vom: 20. Jan., Seite 1138-47
1. Verfasser: Larionova, Joulia (VerfasserIn)
Weitere Verfasser: Guari, Yannick, Blanc, Christophe, Dieudonne, Philippe, Tokarev, Alexei, Guerin, Christian
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2009
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article 1-dodecyl-3-methylimidazolium tetrafluoroborate Borates Cyanides Imidazoles Ions Organometallic Compounds Polymers Chromium 0R0008Q3JB mehr... Manganese 42Z2K6ZL8P
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520 |a Size controlled cyano-bridged coordination polymer nanoparticles Mn1.5[Cr(CN)6] have been synthesized and organized at the nanolevel by using the room temperature ionic liquid crystal (ILC) C12-MIMBF4. The as-obtained material was studied by transmission electron microscopy (TEM), differential scanning calorimetry (DSC), optical microscopy, and X-ray diffraction. These analyses reveal the presence of a long-range organization of cyano-bridged nanoparticles at the nanoscale level within the ILC phase. The magnetic study of these nanoparticles reveals an appearance of a nanocluster-glass-like regime caused by magnetostatic interactions between neighboring nanoparticles. The properties of these organized nanoparticles have been compared with the properties of nanoparticles of the same composition and stoichiometry obtained and randomly dispersed into the isotropic IL C10-MIMBF4 
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700 1 |a Guari, Yannick  |e verfasserin  |4 aut 
700 1 |a Blanc, Christophe  |e verfasserin  |4 aut 
700 1 |a Dieudonne, Philippe  |e verfasserin  |4 aut 
700 1 |a Tokarev, Alexei  |e verfasserin  |4 aut 
700 1 |a Guerin, Christian  |e verfasserin  |4 aut 
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