Phosphorescence enhancement triggered by pi stacking in solid-state [Cu(N-N)(P-P)]BF4 complexes

In this article, we report a phosphorescence enhancement phenomenon of [Cu(N-N)(P-P)]BF4 complexes in the solid state. The phosphorescence enhancement phenomenon is composed of three features: (1) an obvious emission blue shift, (2) a greatly enhanced photoluminescence quantum yield, and (3) a longe...

Ausführliche Beschreibung

Bibliographische Detailangaben
Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 25(2009), 4 vom: 17. Feb., Seite 2068-74
1. Verfasser: Zhang, Liming (VerfasserIn)
Weitere Verfasser: Li, Bin, Su, Zhongmin
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2009
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article Research Support, Non-U.S. Gov't Luminescent Agents Organometallic Compounds Copper 789U1901C5
LEADER 01000naa a22002652 4500
001 NLM185998933
003 DE-627
005 20231223173453.0
007 cr uuu---uuuuu
008 231223s2009 xx |||||o 00| ||eng c
024 7 |a 10.1021/la803822s  |2 doi 
028 5 2 |a pubmed24n0620.xml 
035 |a (DE-627)NLM185998933 
035 |a (NLM)19170602 
040 |a DE-627  |b ger  |c DE-627  |e rakwb 
041 |a eng 
100 1 |a Zhang, Liming  |e verfasserin  |4 aut 
245 1 0 |a Phosphorescence enhancement triggered by pi stacking in solid-state [Cu(N-N)(P-P)]BF4 complexes 
264 1 |c 2009 
336 |a Text  |b txt  |2 rdacontent 
337 |a ƒaComputermedien  |b c  |2 rdamedia 
338 |a ƒa Online-Ressource  |b cr  |2 rdacarrier 
500 |a Date Completed 31.03.2009 
500 |a Date Revised 21.11.2013 
500 |a published: Print 
500 |a Citation Status MEDLINE 
520 |a In this article, we report a phosphorescence enhancement phenomenon of [Cu(N-N)(P-P)]BF4 complexes in the solid state. The phosphorescence enhancement phenomenon is composed of three features: (1) an obvious emission blue shift, (2) a greatly enhanced photoluminescence quantum yield, and (3) a longer excited-state lifetime. Systematic analyses prove that the main cause of this phenomenon is nonradiative process suppression triggered by the pi stacking between [Cu(N-N)(P-P)]BF4 molecules. The phosphorescence enhancement widely exists in [Cu(N-N)(P-P)]BF4 complexes because of the pi surfaces in their diimine ligands 
650 4 |a Journal Article 
650 4 |a Research Support, Non-U.S. Gov't 
650 7 |a Luminescent Agents  |2 NLM 
650 7 |a Organometallic Compounds  |2 NLM 
650 7 |a Copper  |2 NLM 
650 7 |a 789U1901C5  |2 NLM 
700 1 |a Li, Bin  |e verfasserin  |4 aut 
700 1 |a Su, Zhongmin  |e verfasserin  |4 aut 
773 0 8 |i Enthalten in  |t Langmuir : the ACS journal of surfaces and colloids  |d 1992  |g 25(2009), 4 vom: 17. Feb., Seite 2068-74  |w (DE-627)NLM098181009  |x 1520-5827  |7 nnns 
773 1 8 |g volume:25  |g year:2009  |g number:4  |g day:17  |g month:02  |g pages:2068-74 
856 4 0 |u http://dx.doi.org/10.1021/la803822s  |3 Volltext 
912 |a GBV_USEFLAG_A 
912 |a SYSFLAG_A 
912 |a GBV_NLM 
912 |a GBV_ILN_22 
912 |a GBV_ILN_350 
912 |a GBV_ILN_721 
951 |a AR 
952 |d 25  |j 2009  |e 4  |b 17  |c 02  |h 2068-74