Tetrapterosides A and B, two new oleanane-type saponins from Tetrapleura tetraptera
2009 John Wiley & Sons, Ltd.
Publié dans: | Magnetic resonance in chemistry : MRC. - 1985. - 47(2009), 3 vom: 15. März, Seite 277-82 |
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Auteur principal: | |
Autres auteurs: | , , , , |
Format: | Article en ligne |
Langue: | English |
Publié: |
2009
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Accès à la collection: | Magnetic resonance in chemistry : MRC |
Sujets: | Journal Article Saponins tetrapteroside A tetrapteroside B |
Résumé: | 2009 John Wiley & Sons, Ltd. From the stem bark of Tetrapleura tetraptera, two new oleanane-type saponins, tetrapteroside A 3-O-{6-O-[(2E,6S)-2,6-dimethyl-6-hydroxyocta-2,7-dienoyl]-beta-D-glucopyranosyl-(1 --> 2)-beta-D-glucopyranosyl-(1 --> 3)-beta-D-glucopyranosyl-(1 --> 4)-[beta-D-glucopyranosyl-(1 --> 2)]-beta-D-glucopyranosyl}-3,27-dihydroxyoleanolic acid (1), and tetrapteroside B 3-O-{ beta-D-glucopyranosyl-(1 --> 2)-6-O-[(E)-feruloyl]-beta-D-glucopyranosyl-(1 --> 3)-beta-D-glucopyranosyl-(1 --> 4)-[beta-D-glucopyranosyl-(1 --> 2)]-beta-D-glucopyranosyl}-3,27-dihydroxyoleanolic acid (2), were isolated. Further extractions from the roots led to the isolation of four known oleanane-type saponins. Their structures were elucidated by the combination of mass spectrometry (MS), one and two-dimensional NMR experiments |
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Description: | Date Completed 20.04.2009 Date Revised 04.02.2009 published: Print Citation Status MEDLINE |
ISSN: | 1097-458X |
DOI: | 10.1002/mrc.2381 |