Temperature-induced microstructural changes in ionic liquid-based microemulsions
In the present contribution, results concerning the effect of temperature on the nonionic surfactant Triton X-100 based 1-butyl-3-methylimidazolium tetrafluoroborate (bmimBF4)-in-cyclohexane and bmimBF4-in-toluene ionic liquid (IL) reverse microemulsions are reported. Dynamic light scattering (DLS)...
| Veröffentlicht in: | Langmuir : the ACS journal of surfaces and colloids. - 1992. - 25(2009), 3 vom: 03. Feb., Seite 1360-5 |
|---|---|
| 1. Verfasser: | |
| Weitere Verfasser: | , , , , |
| Format: | Online-Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2009
|
| Zugriff auf das übergeordnete Werk: | Langmuir : the ACS journal of surfaces and colloids |
| Schlagworte: | Journal Article |
| Zusammenfassung: | In the present contribution, results concerning the effect of temperature on the nonionic surfactant Triton X-100 based 1-butyl-3-methylimidazolium tetrafluoroborate (bmimBF4)-in-cyclohexane and bmimBF4-in-toluene ionic liquid (IL) reverse microemulsions are reported. Dynamic light scattering (DLS) along with freeze-fracture transmission electron microscopy (FF-TEM) measurements revealed that the sizes of single microemulsion droplets increased with increasing temperature. However, a decreased temperature led to the appearance of droplet clusters, which have also been observed previously when the single microemulsion droplets were swollen by added bmimBF4 to a certain extent (Gao, Y. A.; Vogit, A.; Hilfert, L.; Sundmacher, K. ChemPhysChem, 2008, 9, 1603-1609). Compared to traditional aqueous microemulsions, IL microemulsions revealed relatively high temperature-independence. The droplet-shaped microstructure was always kept in a large range of temperature. The temperature-independence is ascribed to the temperature-insensitive electrostatic attraction between the solubilized bmimBF4 and Triton X-100, which was considered to be the driving force for solubilizing bmimBF4 into the cores of Triton X-100 aggregates. Two-dimensional rotating frame nuclear Overhauser effect (NOE) experiments (ROESY) further confirmed the microstructural change with temperature |
|---|---|
| Beschreibung: | Date Completed 05.03.2009 Date Revised 27.01.2009 published: Print Citation Status PubMed-not-MEDLINE |
| ISSN: | 1520-5827 |
| DOI: | 10.1021/la803452m |