Laccase-catalyzed removal of diphenylamine from synthetic wastewater

The priority pollutant lists of both the U.S. Environmental Protection Agency (U.S. EPA) and the European Union (EU) include diphenylamine (DPA), a contaminant found in wastewater of various industries. This work demonstrates the potential of using enzymatic treatment to remove DPA from buffered syn...

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Veröffentlicht in:Water environment research : a research publication of the Water Environment Federation. - 1998. - 80(2008), 11 vom: 15. Nov., Seite 2118-24
1. Verfasser: Saha, Beeta (VerfasserIn)
Weitere Verfasser: Taylor, K E, Bewtra, J K, Biswas, N
Format: Aufsatz
Sprache:English
Veröffentlicht: 2008
Zugriff auf das übergeordnete Werk:Water environment research : a research publication of the Water Environment Federation
Schlagworte:Journal Article Research Support, Non-U.S. Gov't Alum Compounds Industrial Waste Water Pollutants, Chemical aluminum sulfate 34S289N54E Sodium Dodecyl Sulfate 368GB5141J Polyethylene Glycols mehr... 3WJQ0SDW1A Diphenylamine 9N3CBB0BIQ Laccase EC 1.10.3.2
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245 1 0 |a Laccase-catalyzed removal of diphenylamine from synthetic wastewater 
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520 |a The priority pollutant lists of both the U.S. Environmental Protection Agency (U.S. EPA) and the European Union (EU) include diphenylamine (DPA), a contaminant found in wastewater of various industries. This work demonstrates the potential of using enzymatic treatment to remove DPA from buffered synthetic wastewater. This treatment method includes oxidative polymerization of DPA using laccase from Trametes villosa, followed by removal of those polymers via adsorptive micellar flocculation (AMF) using sodium lauryl sulfate (SDS) and alum. Researchers investigated the effects of pH, laccase concentration, molecular mass, and concentration of polyethylene glycol (PEG) in continuously stirred batch reactors to achieve 95% substrate conversion in three hours. Treatment of 0.19 mM DPA was best at pH 7 and an enzyme concentration from 0.0025 to 0.0075 standard activity unit/mL. Except for PEG400 optimum enzyme and PEG concentrations decreased with an increase in PEG molecular mass. Optimum AMF conditions were pH 3.0 to 6.5, 200 mg/L of SDS, and 150 mg/L of alum 
650 4 |a Journal Article 
650 4 |a Research Support, Non-U.S. Gov't 
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650 7 |a Industrial Waste  |2 NLM 
650 7 |a Water Pollutants, Chemical  |2 NLM 
650 7 |a aluminum sulfate  |2 NLM 
650 7 |a 34S289N54E  |2 NLM 
650 7 |a Sodium Dodecyl Sulfate  |2 NLM 
650 7 |a 368GB5141J  |2 NLM 
650 7 |a Polyethylene Glycols  |2 NLM 
650 7 |a 3WJQ0SDW1A  |2 NLM 
650 7 |a Diphenylamine  |2 NLM 
650 7 |a 9N3CBB0BIQ  |2 NLM 
650 7 |a Laccase  |2 NLM 
650 7 |a EC 1.10.3.2  |2 NLM 
700 1 |a Taylor, K E  |e verfasserin  |4 aut 
700 1 |a Bewtra, J K  |e verfasserin  |4 aut 
700 1 |a Biswas, N  |e verfasserin  |4 aut 
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