Non-electrostatic building of biomimetic cellulose-xyloglucan multilayers

Layer-by-layer assembly was used to build thin films, consisting of multiple layers alternating cellulose nanocrystals and xyloglucan, benefiting from the strong non-electrostatic cellulose-xyloglucan interaction. Data from atomic force microscopy and neutron reflectivity showed that these well-defi...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1985. - 25(2009), 7 vom: 07. Apr., Seite 3920-3
1. Verfasser: Jean, Bruno (VerfasserIn)
Weitere Verfasser: Heux, Laurent, Dubreuil, Frédéric, Chambat, Gérard, Cousin, Fabrice
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2009
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article Glucans Polysaccharides Xylans xyloglucan 37294-28-3 hemicellulose 8024-50-8 Cellulose 9004-34-6
Beschreibung
Zusammenfassung:Layer-by-layer assembly was used to build thin films, consisting of multiple layers alternating cellulose nanocrystals and xyloglucan, benefiting from the strong non-electrostatic cellulose-xyloglucan interaction. Data from atomic force microscopy and neutron reflectivity showed that these well-defined films exhibited a thickness increasing linearly with the number of layers, without increase in surface roughness. These "green" nanocomposite films, reminiscent of plant cell wall, are composed of a regular stack of single layers of cellulose nanocrystals separated by very thin xyloglucan spacers. Such architecture differs from the one formed by cellulose/polycations multilayers, where the cellulose phase itself consists of a double layer
Beschreibung:Date Completed 22.09.2009
Date Revised 28.08.2009
published: Print
Citation Status MEDLINE
ISSN:1520-5827
DOI:10.1021/la802801q